Journal of South China University of Technology (Natural Science Edition) ›› 2007, Vol. 35 ›› Issue (6): 101-105.

• Chemistry & Chemical Engineering • Previous Articles     Next Articles

Properties and Structure of Soy Protein Plastic with Different Formamide Contents

Zou Wen-zhong  Wen Qi-biao  Yang Xiao-quan  Chen Zhong   

  1. School of Light IndustIγand Food Sciences , South China Univ. of Tech. , Guangzhou 510640 , Guangdong , China
  • Received:2006-08-30 Online:2007-06-25 Published:2007-06-25
  • Contact: 邹文中(1977-),男,博士生,主要从事生物高分子材料研究. E-mail:zouwenzhong@163.com
  • About author:邹文中(1977-),男,博士生,主要从事生物高分子材料研究.
  • Supported by:

    广东省"十五"攻关农产品重大专项基金项目(2001 BA501A02)

Abstract:

Soy protein and formamide were mixed at different ratios and were hot press-molded to produce soy protein plastic. The properties , structure and morphology of the plastic were then investigated by means of tensile test ,thermogravimetric analysis , dynamic mechanical thermal analysis , Fourier-transform infrared spectroscopy , and scanning electron microscopy. The results show that (1) the soy protein plastic with a formamide content (mass
fraction) of 20% has a maximum elongation of 269. 66% , which is 77 times that of pure soy protein plastic; (2) the temperature for the maximum mass loss of the plastic with 20% of formamide is much higher than the boiling point of pure formamide; and (3) the water absorption and glass transition temperature of the formamide-plasticized plastic decrease with the increase in formamide content , while the height of loss peak increases. It is also indicated by FTIR that there exist hydrogen bonds between the plasticizer and the soy proteins , which breaks the hydrogen bonds among the protein molecules. Furthermore , the SEM results prove that the introduction of formamide can greatly improve the microstructure and flexibility of soy protein plastic.

Key words: soy protein, forτnamide, plastic, plasticizer, property, structure