Microstructure and High Temperature Deformation Resistance of Nickel-Based Coating on TC4 Surface

doi:10.12141/j.issn.1000-565X.240094

Abstract

Abstract:

In order to study the high temperature and deformation resistance of laser cladding coating on TC4 surface, different proportions of nickel-metal-multi-ceramic composite coatings were prepared on TC4 matrix by laser cladding technology. And GH4169 nickel-based superalloy powder was taken as the base powder, HfC, ZrC, TaC and NbC transition carbides as the reinforcing phase. The microstructure, hardness and high temperature deformation resistance of coatings with different multi-component ceramic powder contents were systematically studied by microstructure characterization and performance experiments. The results show that the addition of carbide ceramic reinforcement phase refines the microstructure of the coating and improves the hardness, and the hardness is the highest when the proportion of ceramic reinforcement phase is 15%, which is 2.54 times that of the substrate. With the increase of temperature, the internal dendrites of the pure nickel-based cladding coating were dissolved and separated, and gradually isoaxed. The dendrite fragmentation appeared in the nickel-based cladding coating supplemented with 15% ceramic powder, and the ceramic strengthened phase dispersed in the cladding layer gathered and grew. Under the conditions of three temperature compression test temperatures (700, 800 and 900 ℃), the maximum equivalent stress and maximum equivalent strain of the specimen appear in the matrix, and compared with the TC4 specimen, the laser cladding specimen produces a stress abrupt change in the coating bonding zone, and the deformation resistance ability of the laser cladding specimen coating is enhanced.

Key words: TC4 titanium alloy, laser cladding, microstructure, microhardness, high temperature compression

CLC Number:

TG174

FU Yuming, LI Changcheng, YAN Maorong, ZHENG Lijuan. Microstructure and High Temperature Deformation Resistance of Nickel-Based Coating on TC4 Surface[J]. Journal of South China University of Technology(Natural Science Edition), 2025, 53(1): 108-117.

Figures/Tables 16

Fig.1

Table 1

Table 2

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

Fig.10

Fig.11

Fig.12

Fig.13

Fig.14

References 21

1	郭鲤，何伟霞，周鹏，等．我国钛及钛合金产品的研究现状及发展前景［J］．热加工工艺，2020，49（22）：22-28.
	GUO Li， HE Weixia， ZHOU Peng，et al ．Research status and development prospect of titanium and titanium alloy products in China［J］．Hot Working Technology，2020，49（22）：22-28.
2	李毅，赵永庆，曾卫东．航空钛合金的应用及发展趋势［J］．材料导报，2020，34（Z1）：280-282.
	LI Yi， ZHAO Yongqing， ZENG Weidong ．Application and development of aerial titanium alloys［J］．Materials Reports，2020，34（Z1）：280-282.
3	张津超，石世宏，龚燕琪，等．激光熔覆技术研究进展［J］．表面技术，2020，49（10）：1-11.
	ZHANG Jin-chao， Shi Shi-hong， GONG Yan-qi，et al ．Research progress of laser cladding technology［J］．Surface Technology，2020，49（10）：1-11.
4	杜学芸，许金宝，宋健．激光熔覆再制造技术研究现状及发展趋势［J］．金属加工（热加工），2020（3）：15-19.
	DU Xueyun， XU Jinbao， SONG Jian ．Research status and development trend of laser cladding remanufacturing technology［J］．MW Metal Forming，2020（3）：15-19.
5	刘录录，孙荣禄．激光熔覆技术及工业应用研究进展［J］．热加工工艺，2007，36（11）：58-61.
	LIU Lu-lu， SUN Rong-lu ．Development of laser cladding technology and industrial application［J］．Hot Working Technology，2007，36（11）：58-61.
6	赵永庆，葛鹏，辛社伟．近五年钛合金材料研发进展［J］．中国材料进展，2020，39（7/8）：527-534，557-558.
	ZHAO Yongqing， GE Peng， XIN Shewei ．Progresses of R＆D on Ti-alloy materials in recent 5 years［J］．Materials China，2020，39（7/8）：527-534，557-558.
7	覃鑫．基于耐磨和耐高温氧化的TC4表面激光熔覆工艺研究［D］．乌鲁木齐：新疆大学，2022.
8	张云龙．Si的添加对TC4合金镍基涂层高温氧化及机械性能的影响［D］．上海：上海工程技术大学，2021.
9	娄燕，李落星，彭大暑．Ti3Al5Mo5V合金在热压缩变形状态下的组织和应力分析［J］．金属热处理，2003，28（4）：36-39.
	LOU Yan， LI Luo-xing， PENG Da-shu ．Analysis on microstructures and stress of Ti3Al5Mo5V alloy at hot compressing deformation state［J］．Heat Treatment of Metals，2003，28（4）：36-39.
10	WANG Z， WANG X， ZHU Z ．Characterization of high-temperature deformation behavior and processing map of TB17 titanium alloy［J］．Journal of Alloys and Compounds，2017，692：149-154.
11	郭建亭．高温合金材料与工程应用［M］．北京：科学出版社，2010.
12	谢佳明，董合凤，张鹏鹏，等．材料表面改性技术的发展研究［J］．科技展望，2016，26（12）：161.
	XIE Jiaming， DONG Hefeng， ZHANG Pengpeng，et al ．Research on the development of material surface modification technology［J］．Science and Technology，2016，26（12）：161.
13	SIMS C T ．高温合金宇航和工业动力用的高温材料［M］．大连：大连理工大学出版社，1992.
14	冯亮，曲恒磊，赵永庆，等．TC21合金的高温变形行为［J］．航空材料学报，2004，24（4）：11-13.
	FENG Liang， QU Heng-lei， ZHAO Yong-qing，et al ．High temperature deformation behavior of TC21 alloy［J］．Journal of Aeronautical Materials，2004，24（4）：11-13.
15	李涵．钛合金表面激光熔覆高熵合金涂层研究［D］．大连：大连理工大学，2017.
16	宁永强，陈泳屹，张俊，等．大功率半导体激光器发展及相关技术概述［J］．光学学报，2021，41（1）：0114001-1-0114001-10.
	NING Yongqiang， CHEN Yongyi， ZHANG Jun，et al ．Brief review of development and techniques for high power semiconductor lasers［J］．Acta Optica Sinica，2021，41（1）：0114001-1-0114001-10.
17	凌妍，钟娇丽，唐晓山，等．扫描电子显微镜的工作原理及应用［J］．山东化工，2018，47（9）：78-79，83.
	LING Yan， ZHONG Jiaoli， TANG Xiaoshan，et，al ．The principle and application of scanning electron microscope［J］．Shangdong Chemical Industry，2018，47（9）：78-79，83.
18	陈向文，庄哲峰，孟素各．激光熔覆不同TiC含量硬质合金层的组织与性能［J］．机电技术，2015（6）：115-118.
	CHEN Xiangwen， ZHUANG Zhefeng， MENG Suge ．Structure and properties of cemented carbide layers with different TiC contents by laser cladding［J］．Mechanical & Electrical Technology，2015（6）：115-118.
19	周军，曾卫东，舒滢，等．热变形参数对Ti-17合金的片状α球化过程的影响［J］．热加工工艺，2005（1）：16-18，41.
	ZHOU Jun， ZENG Wei-dong， SHU Ying，et al. Influence of hot processing parameters on globularization of lamellar α in Ti-17 alloy［J］．Hot Working Technology，2005（1）：16-18，41.
20	谭金花．TC4合金表面激光熔覆钛基复合涂层组织及性能研究［D］．天津：天津工业大学，2020.
21	种润，郭绍庆，张文扬，等．GH4169合金激光增材制造过程热-力发展数值模拟［J］．焊接，2021（3）：13-21，61-62.
	ZHONG Run， GUO Shaoqing， ZHANG Wenyang，et al ．Numerical simulation of thermal-mechanical development of GH4169 alloy in laser additive manufacturing process［J］．Welding & Joining，2021（3）：13-21，61-62.

粉末编号	质量分数/%
粉末编号	ZrC	NbC	HfC	TaC	GH4169
A	0.00	0.00	0.00	0.00	100.00
B	1.25	1.25	1.25	1.25	95.00
C	2.50	2.50	2.50	2.50	90.00
D	3.75	3.75	3.75	3.75	85.00

[1]	ZHENG Lijuan, XIE Yinkai, ZHANG Kuo, et al. Preparation and performance study of high temperature oxidation cladding coating on TC4 surface [J]. Journal of South China University of Technology(Natural Science Edition), 2025, 53(3): 97-104.
[2]	FU Yuming, MA Shunxin, LIU Shaofeng, et al. Microstructure and Properties of Laser Cladding Hard Composite Coating on TC4 Surface [J]. Journal of South China University of Technology(Natural Science Edition), 2024, 52(3): 10-17.
[3]	LUO Zhen, SU Jie, WANG Xiaohua, et al. Research Progress Analysis of Laser-Arc Hybrid Welding of Aluminum Alloys [J]. Journal of South China University of Technology(Natural Science Edition), 2024, 52(3): 57-74.
[4]	ZHENG Lijuan, HU Zitao, LIU Shaofeng, et al. Preparation and Analysis of Laser Cladding Hard Coating on TC4 Surface [J]. Journal of South China University of Technology(Natural Science Edition), 2023, 51(6): 146-152.
[5]	ZHANG Heng, HUANG Junguang, LI Weike, et al. Influence of Electroosmosis-Calcium Chloride Treatment on the Deformation of Sodium Sulfate Saline Soil [J]. Journal of South China University of Technology(Natural Science Edition), 2023, 51(4): 53-60.
[6]	YU Qijun, MA Ting, ZHANG Tongsheng, et al.. Effect of Particle Size on Hydration Kinetics and Microstructure Development of Recycled Brick Powder-Cement Pastes [J]. Journal of South China University of Technology(Natural Science Edition), 2023, 51(11): 63-73.
[7]	YIN Suhong, LI Yanmei, DING Weimin, et al.. Effect of Pyrite Tailings Mineralizer on Calcination and Properties of Cement Clinker [J]. Journal of South China University of Technology(Natural Science Edition), 2023, 51(11): 74-81.
[8]	TAN Haibing, LI Shu, WANG Jing, et al. Influence of Solution Temperature on Microstructure and Mechanical Property of GH4099 Alloy [J]. Journal of South China University of Technology(Natural Science Edition), 2022, 50(8): 136-143.
[9]	LIAO Yanfen, QIU Mengze, CHEN Shunkai, et al . Experimental Study on Thermal Drying Characteristics and Pollutant Discharge Law of Municipal Sludge [J]. Journal of South China University of Technology(Natural Science Edition), 2022, 50(8): 92-101.
[10]	KANG Lan, WU Bin, CHEN Zhibang. Mechanical Property of Reworked Part of Locally Corroded Steel Plate Repaired with Laser Cladding Technology [J]. Journal of South China University of Technology(Natural Science Edition), 2022, 50(5): 137-146.
[11]	CHEN Weiping, LI Bing, LING Zicheng, et al. Influence of Ce Addition on Microstructure and Corrosion Resistance to Molten Aluminum of Fe-Cr-B Alloys [J]. Journal of South China University of Technology (Natural Science Edition), 2021, 49(9): 73-79.
[12]	WEI Xiaolan, LIN Guoqing, DING Jing, et al. Simulation and Experiment Investigation into Specific Heat Capacity Enhancement of Nitrate Molten Salt Nanofluid [J]. Journal of South China University of Technology (Natural Science Edition), 2021, 49(9): 46-55.
[13]	CAO Faxiang, KONG Jinxing, DU Dongxing. Research on Surface Properties of Nd: YAG Crystal Modified by Plasma Jet [J]. Journal of South China University of Technology (Natural Science Edition), 2021, 49(3): 55-61.
[14]	ZHOU Tao, HE Lin, TIAN Pengfei, et al. Prediction Model of Microstructure Evolution in Shear Zone During Cutting Process [J]. Journal of South China University of Technology (Natural Science Edition), 2021, 49(1): 82-92.
[15]	XU Daofen, CHEN Kanghua, XING Jun, et al. Microstructure and Corrosion Behavior of 2219 Aluminum Alloy Forging's Joint by TIG Welding [J]. Journal of South China University of Technology (Natural Science Edition), 2020, 48(3): 116-125.