华南理工大学学报(自然科学版) ›› 2018, Vol. 46 ›› Issue (2): 131-139.doi: 10.3969/j.issn.1000-565X.2018.02.019

• 材料科学与技术 • 上一篇    下一篇

高频电场与正应力场协同作用下聚合物的热响应特性

杨智韬 童益彰 徐文华 殷小春 张桂珍 瞿金平    

  1. 华南理工大学 聚合物新型成型装备国家工程研究中心∥聚合物成型加工工程教育部重点实验室,广东 广州 510640
  • 收稿日期:2017-09-29 修回日期:2017-12-19 出版日期:2018-02-25 发布日期:2018-01-02
  • 通信作者: 殷小春( 1975-) ,男,博士,副教授,主要从事聚合物成型理论及装备研究 E-mail:xcyin@scut.edu.cn
  • 作者简介:杨智韬( 1981-) ,男,博士,副教授,主要从事聚合物新型成型理论及装备研究.
  • 基金资助:
    国家自然科学基金青年基金资助项目( 51403068, 51505153) ;华南理工大学中央高校基本科研业务费专项资金 资助项目( 2017ZD013) 

Study on Thermal-Response Characteristic of Polymer Materials to Synergism of High-Frequency Electric Field and Normal Stress Field
 

 YANG Zhitao TONG Yizhang XU Wenhua YIN Xiaochun ZHANG Guizhen QU Jinping    

  1.   National Engineering Research Center of Novel Equipment for Polymer Processing∥Key Laboratory of Polymer Processing Engineering of the Ministry of Education,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2017-09-29 Revised:2017-12-19 Online:2018-02-25 Published:2018-01-02
  • Contact: 殷小春( 1975-) ,男,博士,副教授,主要从事聚合物成型理论及装备研究 E-mail:xcyin@scut.edu.cn
  • About author:杨智韬( 1981-) ,男,博士,副教授,主要从事聚合物新型成型理论及装备研究.
  • Supported by:
      Supported by the Youth Fund of the National Natural Science Foundation of China( 51403068, 51505153) 

摘要: 目前高分子材料成型方法都采用高温塑化、低温成型的成型机理进行加工. 这一 过程消耗了大量的能量,并造成聚合物及其添加剂的热降解,降低了塑料的性能和可回收 性. 因此,文中在聚合物热压成型加工中引入高频电场,使物料在正应力和高频电场协同 作用下实现低温塑化,研究物料在高频电场中发生热响应的压力、温度依赖性,以及在临 界塑化温度点下制备的聚合物片材的力学性能,建立合理的温升模型. 研究表明: 材料极 性越强,其介电损耗越高,物料吸热能力越强; 极性材料和非结晶性聚合物吸热量随成型 压力的增大而增大,而非极性的结晶性聚合物吸热量存在最佳吸热压力点;均聚物具有最 佳吸热温度点,而多相的共聚物吸热量随加工温度呈指数增长;施加高频电场试样的拉伸 性能显著提升,证实了协同低温塑化行为的存在. 

关键词: 高频电场, 正应力, 温升模型, 压力依赖性, 温度依赖性, 低温塑化 

Abstract:  Currently,polymer materials are processed by high temperature plasticizing and low temperature molding. These processing needs to spend a lot of energy and causes the degradation of polymers and additives, reducing product performances and recovery. Therefore,this article introduces highfrequency electric field into hotpressing process of polymers,making the materials plasticize in synergism of normal stress field and highfrequency electric field at low temperature. The dependence of pressure and temperature on thermalresponse of polymer materials to the high frequency electric field,as well as the mechanical properties of pure polymer plates which are prepared at critical plasticizing temperature point, is studied in depth; a model of temperaturerising is also reasonably established. The results show that the stronger polarity of polymer materials, the higher dielectric loss and absorbed heat will be; the absorbed heat of polar materials and amorphous polymer are positively related to the processing pressure,while the absorbed heat of non-polar crystalline materials have the best pressure point in which materials absorb the maximal heat. Homo-polymer have the best temperature points for heat absorption,while the absorbed heat of copolymer exponentially increase with the processing temperature rising. The tensile properties of specimens with highfrequency electric field improved significantly when compared to the specimens without highfrequency electric field,proving the existence of plasticizing behavior at low temperature under the synergism of normal stress field and  highfrequency electric field

Key words: highfrequency electric field, positive stress, model of temperaturerising, pressure dependence, temperature dependence, lowtemperature plasticization 

中图分类号: