Journal of South China University of Technology(Natural Science Edition) ›› 2003, Vol. 31 ›› Issue (9): 53-56.

• Chemistry & Chemical Engineering • Previous Articles     Next Articles

Kinetics of Adsorption of Nickel (Ⅱ) Ion on Fibre Containing Amidoxime Groups

Tao Ting-xian 1 Wu Zh-i chuan 1 Sun Zh-i juan 2    

  1. 1.Dept.of Biochemical Engineering‚Anhui University of Technology and Science‚Wuhu241000‚China; 2.College of Chemical Engineering‚South China Univ.of Tech.‚Guangzhou510640‚China
  • Online:2003-09-20 Published:2022-05-20

Abstract: The adsorption of Ni 2+ on the fibre containing amidoxime groups in different initial concentration Ni 2+ aqueous solution is studied‚and it was found that the bonding between Ni 2+ and amidoxime groups was in accordance with the Freundlich isotherm.The reaction order was determined by infinitesimal calculus‚based on the relationship between the adsorption time and the concentration of Ni 2+.To determine reaction rate constants( k)‚the adsorption of Ni 2+ of 0.033mol·L -1(initial concentration) on fibre containing amidoxime groups was also studied at different temperature.According to the correlation of k with the temperature and Arrhenius equation‚the activation energy was obtained.The results indicate that the adsorption kinetics accorded with the character of the first order reaction: with the reaction rate equation being c=c0e -kt‚the equation of reaction rate constant k=0.1716e -Ea/RT‚and the activation energy Ea=13.52kJ/mol. 

Key words:  , fibre containing amidoxime groups;Nickel(Ⅱ)ion;adsorption;kinetic

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