Journal of South China University of Technology (Natural Science Edition) ›› 2007, Vol. 35 ›› Issue (11): 95-99.

• Chemistry & Chemical Engineering • Previous Articles     Next Articles

Change of Interface Properties Caused by CTAB Adsorption on Surface of Nano-Sized Calcium Carbonate

Tang Yan-jun  Li You-ming  Li Bin   

  1. State Key Laboratory of Pulp and Paper Engineering, South China Univ. of Tech. , Guangzhou 510640 , Guangdong , China
  • Received:2006-10-30 Online:2007-11-25 Published:2007-11-25
  • Contact: 李友明,教授. E-mail: pperc@scut.edu.cn E-mail:www-tang@163.com
  • About author:唐艳军(1977- ),男,博士生,主要从事纸张涂布加工及特种纸的研究.
  • Supported by:

    国家自然科学基金资助项目(202760125)

Abstract:

In this paper , cetyl trimethyl ammonium bromide (CTAB) was used to perform the surface modification of nano-sized calcium carbonate. Then , FT-IR , XRD and TG-DTG were adopted to characterize the samples before and after the modification. Moreover , the Zeta potential , Brookfield viscosity , oil-absorbed value and specific surface area of the samples were measured to evaluate the modification effect. The results indicate 出at the modification by CT AB may result in a chemical adsorption on the surface of nano-sized calcium carbonate , and that the modification with 2.0% of CTAB may cause great changes of the interface characteristics. Concretely , the Zeta potential changes form negative to positive , the Brookfield viscosity greaùy decreases , the oil-absorbed value decreases from 96. 8g to 53. 1g , and the specific surface area increases from 20. 1m2/g to 26. 0m2/g.

Key words: calcium carbonate, cetyl trimethyl ammonium bromide, modification, interface property, dispersion