Simultaneous Desulfurization and Denitrification from Flue Gas by Using Urea/ Additive Solution( Ⅰ) :Kinetic Equation of Urea Consumption in Absorption Reaction

Journal of South China University of Technology(Natural Science Edition) ›› 2004, Vol. 32 ›› Issue (1): 37-40.

Previous Articles Next Articles

Simultaneous Desulfurization and Denitrification from Flue Gas by Using Urea/ Additive Solution( Ⅰ) :Kinetic Equation of Urea Consumption in Absorption Reaction

Cen Chao-ping¹ Gu Guo-bang²

1．South China Institute of Environmental ScienceSEPAGuangzhou510655GuangdongChina；
2．Dept．of Applied ChemistrySouth China Univ．of Tech．Guangzhou510640GuangdongChina

Received:2003-03-13 Online:2004-01-20 Published:2015-09-07
Contact: 岑超平（1964－）女工学博士研究员主要从事环境工程的研究及设计． E-mail:cpcen＠scies.com.cn
About author:岑超平（1964－）女工学博士研究员主要从事环境工程的研究及设计．

Abstract

Abstract: The kinetic equation of urea consumption in absorption reaction was studied in the process of simulta-neous desulfurization and denitrification from flue gas by using urea／additive solution．The experimental results how that the relationship between urea concentration and time is linearand the reaction order is zero．The rate constant k of absorption reaction of urea solution without additive is0．8571mmol·L －1 min －1 while k is res-pectively1． 945mmo1·L －1 ·min －1 and1．1521mmo1·L －1 ·min －1 with the additives of ethylenediamine and ammonium phosphate．The rate constant of absorption reaction in the simultaneous desulfurization and denitrification is greater than the sum of those obtained in separate desulfurization and denitrificationwhich shows the synergism in the process of simultaneous desulfurization and denitrification．

Key words: urea, additive, flue gas, desulfurization, denitrification, kinetic equation

CLC Number:

TM461.3

Cen Chao-ping Gu Guo-bang. Simultaneous Desulfurization and Denitrification from Flue Gas by Using Urea/ Additive Solution( Ⅰ) :Kinetic Equation of Urea Consumption in Absorption Reaction[J]. Journal of South China University of Technology(Natural Science Edition), 2004, 32(1): 37-40.

[1]	LIU Dingping SHEN Kang. Influence of Atomization and Evaporation of Desulfurization Wastewater on Cement Furnace Pollutants [J]. Journal of South China University of Technology (Natural Science Edition), 2021, 49(11): 80-86.
[2]	LIN Yu, CHEN Dezhen. Numerical Simulation of the Gas-Liquid Two Phases Flow and Evaporative Cooling Process in the Desulphurization Absorption Tower at Different Spraying Layers Operation Modes [J]. Journal of South China University of Technology(Natural Science Edition), 2019, 47(3): 20-29.
[3]	LIAO Junxu LU Hao DAI Kangxu CAO Hua ZHAO Hongbin HAN Lifen XU Yongjun FANG Yutang. Tribological Properties of Nitrogen-Containing Lubricant Additives [J]. Journal of South China University of Technology (Natural Science Edition), 2018, 46(7): 70-78.
[4]	LI Zhili HUANG Wenxing GE Yuanyuan. Adsorption Properties of Graphene Oxide on Chlortetracycline and Methylene Blue in Water [J]. Journal of South China University of Technology (Natural Science Edition), 2018, 46(7): 62-69,78.
[5]	Zuo Xi Li Wen-fang Mu Song-lin. Influence of Additives on Morphology and Performance of Colored Ti-Zr Conversion Coating at Room Temperature [J]. Journal of South China University of Technology (Natural Science Edition), 2014, 42(10): 7-13.
[6]	Gao Wen-hua Chen Ke-fu Yang Ren-dang Yang Fei . Properties of Reconstituted Tobacco with Rheological Additives [J]. Journal of South China University of Technology (Natural Science Edition), 2014, 42(10): 95-101.
[7]	Qu Jin-qing Wan Wen Yong Xue Su Ming-jian Yan Yi-chen Liu Rui-yuan. Synthesis and Anion Recognition Properties of Sulfonylurea Receptor [J]. Journal of South China University of Technology (Natural Science Edition), 2013, 41(3): 142-146.
[8]	Luo Jian- fei Lin Wei- tie. Research Progress of Ammonia- Oxidizing Archaea [J]. Journal of South China University of Technology (Natural Science Edition), 2013, 41(12): 107-114.
[9]	Deng Yong-hong Xiao Liang Feng Xin-jia Yang Dong-jie Qiu Xue-qing. Effect of Urea on Solution Behaviors and Adsorption Characteristics ofAlkali Lignin [J]. Journal of South China University of Technology (Natural Science Edition), 2013, 41(1): 95-99.
[10]	Ye Dai-yong Zhou Liu-jia. Nanocellulose Whiskers as Thickening Rheological Agent for Waterborne Polyurethane Dispersion [J]. Journal of South China University of Technology (Natural Science Edition), 2010, 38(9): 63-67,74.
[11]	Luo Zhi-gang Yang Jing-feng Wang Min-ni . Enzymatic Properties of Urease Immobilized on Enzymic Dialdehyde Starch [J]. Journal of South China University of Technology (Natural Science Edition), 2010, 38(8): 51-55.
[12]	Su Da-gen Zhao Yong . Preparation of Ceramics from Desulphurization Slag and Waste Stone Powders [J]. Journal of South China University of Technology (Natural Science Edition), 2010, 38(7): 117-121.
[13]	Xi Yan-hong Mao Jun Fan Hong-ming Zhao Yao-hua Zhu Sheng. Safety Velocity of On-Fire Train Moving in Subway Tunnel [J]. Journal of South China University of Technology (Natural Science Edition), 2010, 38(3): 25-30，36.
[14]	Chai Xiu-li Zeng De-chang Liu Gui-xiong Yu Hong-ya Zhong Xi-chun Liu Wen-jie . Modeling and Numerical Calculation of Asymmetrical Giant Magneto-Impedance Effect of Ribbons [J]. Journal of South China University of Technology (Natural Science Edition), 2009, 37(2): 35-39,44.
[15]	Chen Miao Wang Dao-bo Wang Zhi-sheng. Design of Non-Fragile H∞ Filter for Time-Delay Jump Systems [J]. Journal of South China University of Technology (Natural Science Edition), 2009, 37(10): 60-65.

Simultaneous Desulfurization and Denitrification from Flue Gas by Using Urea/ Additive Solution( Ⅰ) :Kinetic Equation of Urea Consumption in Absorption Reaction

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments