华南理工大学学报(自然科学版) ›› 2015, Vol. 43 ›› Issue (7): 20-27.doi: 10.3969/j.issn.1000-565X.2015.07.004

• 材料科学与技术 • 上一篇    下一篇

PS/Talc复合材料的制备及其超临界CO2挤出发泡

余鹏 陈斌艺 王彬彬 黄岸 彭响方   

  1. 华南理工大学 聚合物新型成型装备国家工程研究中心//聚合物成型加工工程教育部重点实验室,广东 广州 510640
  • 收稿日期:2014-11-24 修回日期:2015-03-30 出版日期:2015-07-25 发布日期:2015-06-03
  • 通信作者: 彭响方( 1966-) ,男,教授,博士生导师,主要从事高分子材料先进成型加工技术与理论、聚合物改性加工理论与成型模具技术研究. E-mail:pmxfpeng@scut.edu.cn
  • 作者简介:余鹏( 1983-) ,男,博士生,主要从事高分子材料微孔发泡研究. E-mail: yupengniao@126.com
  • 基金资助:
    国家自然科学基金资助项目( 51073061,21174044) ; 广东省自然科学基金资助项目( S2013020013855) ; 国家“973”计划项目( 2012CB025902)

Preparation of PS /Talc Composites and Its Extrusion Foaming Using Supercritical CO2

Yu Peng Chen Bin-yi Wang Bin-bin Huang An Peng Xiang-fang   

  1. National Engineering Research Center of Novel Equipment for Polymer Processing//Key Laboratory of Polymer Processing Engineering of the Ministry of Education,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2014-11-24 Revised:2015-03-30 Online:2015-07-25 Published:2015-06-03
  • Contact: 彭响方( 1966-) ,男,教授,博士生导师,主要从事高分子材料先进成型加工技术与理论、聚合物改性加工理论与成型模具技术研究. E-mail:pmxfpeng@scut.edu.cn
  • About author:余鹏( 1983-) ,男,博士生,主要从事高分子材料微孔发泡研究. E-mail: yupengniao@126.com
  • Supported by:
    Supported by the National Natural Science Foundation of China ( 51073061,21174044) ,Natural Science Foundation of Guangdong Province of China (S2013020013855) and the National Program on Key Basic Research Project of China ( 973 Program) ( 2012CB025902)

摘要: 利用混合效果优异的平行三螺杆挤出机制备了聚苯乙烯/活性滑石粉( PS /Talc) 复合材料,分析了Talc 在PS 基体中的分散性,研究了复合材料的力学性能和热稳定性, 并通过挤出发泡正交试验,探讨影响泡孔结构的主次因素. 研究结果表明,三螺杆挤出混 炼能很好地改善Talc 在基体中的分散效果,当Talc 含量在6% 以下时,能够均匀分散在 PS 基体中; 拉伸强度、冲击强度以及断裂伸长率随着Talc 含量增加呈现先增加后减小的 趋势,当Talc 含量为6%时,拉伸强度、冲击强度以及断裂伸长率出现极大值; 随着Talc 含 量增加,弯曲强度下降,弯曲模量增加; Talc 能够增加复合材料的热稳定性,当Talc 的填 充量为10%时,复合材料的热稳定最好; 挤出发泡正交实验结果表明,影响PS /Talc 复合 材料发泡行为的主次因素为: Talc 含量、口模压力、口模温度; 当Talc 填充量为8% 时,得 到的泡孔尺寸最小,泡孔密度最大,它们分别为12.4μm 和2.4 × 108个/cm3

关键词: 聚苯乙烯, 滑石粉, 复合材料, 挤出发泡, 正交试验, 微观形态

Abstract: Polystyrene /active Talc ( PS /Talc) composites were prepared by means of a parallel triple-screw extruder with excellent mixing ability. Then, the dispersion of Talc in PS matrix was analyzed, and the mechanical properties and thermal stability of PS /Talc composites were investigated. Meanwhile, the key factors affecting cell structure were discussed via extrusion foaming orthogonal experiments. The results show that (1) the dispersion of Talc in PS matrix is improved by the triple screw extruder, and Talc can be dispersed in PS matrix evenly when the Talc content is below 6%; (2) the tensile strength, the impact strength and the elongation at break first increase and then decrease as the Talc content reduces, and they all reach the maximum when the Talc content is 6%; (3) with the increase of the Talc content, the flexural strength decreases while the flexural modulus increases; (4) the addition of Talc can enhance the thermal stability of PS /Talc composites, and the thermal stability reaches the maximum at the Talc content of 10%; (5) the primary factor affecting the foaming behavior of PS /Talc composites is the Talc content, which is followed by the die pressure and the die temperature; and (6) when the Talc content is 8%, the minimum cell size and the maximum cell density are obtained, which are 12.4μm and 2.4 × 108 cells /cm3 ,respectively.

Key words: polystyrene, Talc, composites, extrusion foaming, orthogonal experiment, micro-morphology

中图分类号: