华南理工大学学报(自然科学版) ›› 2012, Vol. 40 ›› Issue (5): 133-138.

• 食品科学与技术 • 上一篇    下一篇

不同温度热解酸化蔗糖制备低聚焦糖

王军 王忠合 薛晓丽 于淑娟   

  1. 华南理工大学 轻工与食品学院,广东 广州 510640
  • 收稿日期:2011-10-09 修回日期:2011-11-22 出版日期:2012-05-25 发布日期:2012-03-31
  • 通信作者: 于淑娟(1955-) ,女,教授,博士生导师,主要从事糖品工程与糖类衍生物研究. E-mail: lfshjyu@scut.edu.cn E-mail:xuehan1981@163.com
  • 作者简介:王军(1981-) ,女,博士生,主要从事糖品工程与糖类衍生物研究.
  • 基金资助:

    国家自然科学基金资助项目( 31071564) ; 粤港关键领域重点突破项目( 2009A020700007) ; 华南理工大学中央高校基本科研业务费专项资金资助项目( 2011ZP009)

Preparation of Sucrose Thermal Oligosaccharides Caramel via Thermolysis of Acided Sucrose at Different Temperatures

Wang Jun  Wang Zhong-he  Xue Xiao-li  Yu Shu-juan   

  1. School of Light Industry and Food Sciences,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2011-10-09 Revised:2011-11-22 Online:2012-05-25 Published:2012-03-31
  • Contact: 于淑娟(1955-) ,女,教授,博士生导师,主要从事糖品工程与糖类衍生物研究. E-mail: lfshjyu@scut.edu.cn E-mail:xuehan1981@163.com
  • About author:王军(1981-) ,女,博士生,主要从事糖品工程与糖类衍生物研究.
  • Supported by:

    国家自然科学基金资助项目( 31071564) ; 粤港关键领域重点突破项目( 2009A020700007) ; 华南理工大学中央高校基本科研业务费专项资金资助项目( 2011ZP009)

摘要: 为拓展热解酸化蔗糖制备低聚焦糖的应用领域,分别考察了不同温度下干法与湿法制备的低聚焦糖的pH 值、特征吸收、褐变程度、糖含量、抗氧化性,并分析了低聚焦糖的主要成分和热稳定性.结果表明: 随着温度升高,干法工艺制备的低聚焦糖的pH 值先升高后缓慢降低,湿法工艺制备的则逐渐降低; 干法工艺制备的低聚焦糖的特征吸收及褐变程度均上升,湿法工艺制备时则在160℃达到最强,分别为3. 151 和2. 128; 两种工艺制备的低聚焦糖的总糖含量逐渐减少,还原糖含量先上升后下降,抗氧化性增强; 低聚焦糖主要成分为蔗糖、蔗果三糖等低聚糖,以及少量的葡萄糖、果糖等; 低聚焦糖的热裂解产物主要有呋喃、呋喃酮、吡唑、吡咯烷、醛、烯和酸酐类.

关键词: 热解, 酸化蔗糖, 低聚焦糖, 成分分析, 热裂解

Abstract:

In order to widen the application of sucrose thermal oligosaccharides caramel ( STOC) prepared by the thermolysis of acided sucrose,the pH value, characteristic absorption,browning degree,sugar content,antioxidant activity of the STOC prepared respectively by dry and wet processes at different temperatures were investigated and the main components as well as the thermal stability of the products were analyzed. The results show that,with the increase of temperature,the pH value of the STOC prepared by dry process first increases and then slowly decreases,but the one by wet process gradually decreases,that the characteristic absorption and browning of the STOC appear a up-trend in dry process and respectively reach the maximum of 3. 151 and 2. 128 at 160℃ in wet process,and that,for the STOC prepared by the two processes,the total sugar content gradually decreases,the reducing sugar content first increases and then decreases,and the antioxidant activity improves. Moreover,it is found that the STOC mainly contains oligosaccharides,such as sucrose and 1-kestose,together with small amount of glucose and fructose,etc.,and that the main compounds obtained from the STOC pyrolysis include furan,furan ketone,pyrazole,pyrrolidine,aldehyde,alkene and anhydride.

Key words: thermolysis, acided sucrose, sucrose thermal oligosaccharides caramel, component analysis, pyrolysis

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