华南理工大学学报(自然科学版) ›› 2008, Vol. 36 ›› Issue (7): 106-110,116.

• 材料科学与技术 • 上一篇    下一篇

二氧化硅增强增韧不饱和聚酯

徐喻琼1  游敏2 瞿金平1 郑小玲2   

  1. 1. 华南理工大学 聚合物新型成型装备国家工程研究中心, 广东 广州 510640; 2. 三峡大学 机械与材料学院, 湖北 宜昌 443002
  • 收稿日期:2006-11-24 出版日期:2008-07-25 发布日期:2008-07-25
  • 通信作者: 徐喻琼(1974-),女,博士生,工程师,主要从事聚合物复合材料加工研究. E-mail:kexy@qdc.com.cn
  • 作者简介:徐喻琼(1974-),女,博士生,工程师,主要从事聚合物复合材料加工研究.
  • 基金资助:

    国家自然科学基金重大项目(10590351),湖北省教育厅科研计划重大项目(2003Z001)

Strengthening and Toughening of Unsaturated Polyester with Silicon Dioxide

Xu Yu-qiong1  You Min2  Qu Jin-ping1  Zheng Xiao-ling2   

  1. 1. National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou 510640, Guangdong, China; 2. College of Mechanical and Material Engineering, China Three Gorges University, Yichang 443002, Hubei, China
  • Received:2006-11-24 Online:2008-07-25 Published:2008-07-25
  • Contact: 徐喻琼(1974-),女,博士生,工程师,主要从事聚合物复合材料加工研究. E-mail:kexy@qdc.com.cn
  • About author:徐喻琼(1974-),女,博士生,工程师,主要从事聚合物复合材料加工研究.
  • Supported by:

    国家自然科学基金重大项目(10590351),湖北省教育厅科研计划重大项目(2003Z001)

摘要: 采用二氧化硅对不饱和聚酯树脂进行增强增韧,发现在所采取的试验条件下,SiO2的添加量对材料性能有显著影响,添加量为8%(质量分数)时拉伸断裂能达最大值,添加量为8%~12%时所得复合材料有较低的固化收缩率.用红外光谱法研究复合材料中分子特征基团的变化及氢键对材料性能的影响,发现在SiO2添加量低于10%时,随添加量增加,不饱和双键和羟基的吸收峰显著增强.

关键词: 不饱和聚酯树脂, 二氧化硅, 复合材料, 拉伸性能

Abstract:

Silicon dioxide was used to strengthen and toughen unsaturated polyester resin. The results show that, in the employed experimental conditions, the performances of the product are greatly affected by the dosage ( mass fraction) of silicon dioxide, that the tension fracture energy reaches the maximum value at a SiO2 dosage of 8% , and that the curing shrinkage rate becomes low at a SiO2 dosage of 8% - 12%. Moreover, FT-IR spectra were used to reveal the effects of the characteristic groups and hydrogen bonds on the performances of the composite. The results indicate that the absorption peaks of unsaturated double bonds and hydroxyls greatly improve with SiO2 dosage when the dosage is less than 10%.

Key words: unsaturated polyester resin, silicon dioxide, composite, tension property