华南理工大学学报(自然科学版) ›› 2006, Vol. 34 ›› Issue (10): 6-10.

• 化学化工、能源 • 上一篇    下一篇

质子交换膜燃料电池运行参数的仿真优化

简弃非 赵永利 刘海燕   

  1. 华南理工大学 汽车工程学院,广东 广州 510640
  • 收稿日期:2005-09-23 出版日期:2006-10-25 发布日期:2006-10-25
  • 通信作者: 简弃非(1963-),男,博士,副教授,主要从事传热传质及工程控制研究 E-mail:tcjqf@scut.edu.CN
  • 作者简介:简弃非(1963-),男,博士,副教授,主要从事传热传质及工程控制研究
  • 基金资助:

    广东省自然科学基金资助项目(013024);广东省科技计划项目(2002C3 1604)

Simulation and Optimization of W orking Parameters of Proton Exchange M embrane Fuel Cell

Jian Qi-fei  Zhao yYong-li  Liu Hai-yan   

  1. School of Automotive Engineering,South China Univ.of Tech.,Guangzhou 510640,Guangdong,China
  • Received:2005-09-23 Online:2006-10-25 Published:2006-10-25
  • Contact: 简弃非(1963-),男,博士,副教授,主要从事传热传质及工程控制研究 E-mail:tcjqf@scut.edu.CN
  • About author:简弃非(1963-),男,博士,副教授,主要从事传热传质及工程控制研究
  • Supported by:

    广东省自然科学基金资助项目(013024);广东省科技计划项目(2002C3 1604)

摘要: 为研究质子交换膜燃料电池(PEMFC)工作温度和反应气体工作压力变化对单体输出性能的影响,通过建立PEMFC单体的电化学模型及系统参数模型,利用Matlab软件,以Mark V型燃料电池发动机为实例,研究了工作温度和反应气体工作压力变化对电池单体输出性能的影响.结果表明:(1)工作温度每提高10 K,单体的平均电压、平均功率将增加3%,在高温阶段增幅略有下降;(2)提高反应气体工作压力同样有利于提高电池的输出性能,但提高幅度受电池本身的限制,其工作压力一般不超过1MPa;(3)PEMFC还具有较好的瞬时过载能力.

关键词: 质子交换膜, 燃料电池, 电化学模型, 稳态, 运行参数, 仿真, 优化

Abstract:

In order to study the effects of working parameters such as the working temperature and the pressure of reactive gases on the output performance of Proton Exchange Membrane Fuel Cell(PEMFC),an electrochemical model and a working parameter model of the cell were established.Then,by taking the Mark V fuel cell engine as an example.the variation of the output performance with the working temperature and the pressure of reactive gases
was simulated with Matlab software.The results show that(1)the mean cell power and voltage increases by 3%for each temperature increment of 10 K,with a slightly decreasing increment in high-temperature conditions;(2)the output perform ance of the cell can be improved by increasing the gas pressure,but the amplitude is limited by the fuel cell whose feasible working pressure is generally not more than 1 MPa;and(3)PEMFC possesses excellent in-stantaneous overloading ability.

Key words: proton exchange membrane, fuel cell, electrochemical model, steady condition, working parameter, simulation;optimization