Materials Science & Technology

Microstructure and Properties of Laser Cladding Hard Composite Coating on TC4 Surface

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  • School of Mechanical Engineering,Yanshan University,Qinhuangdao 066004,Hebei,China
付宇明(1971-),男,博士,教授,主要从事激光熔覆及高熵合金新材料制备等研究。Email: mec9@ysu.edu.cn

Received date: 2023-02-21

  Online published: 2023-04-04

Supported by

the Nature Science Foundation of Hebei Province(E2021203218)

Abstract

TC4 is widely used in aerospace field due to its high specific strength, good corrosion resistance and light weight. However, its disadvantages such as large friction coefficient and poor wear resistance greatly limit its application range. In view of the shortcomings of low hardness and poor wear resistance of TC4, a 4 kW high-power Laser4000 semiconductor laser was used to prepare different proportions of steel-based metal-ceramic hard coatings on the surface of TC4 by laser cladding technology with transition family refractory carbides HfC, TaC and ZrC as reinforcing phases and H13 steel-based powder as base powder. Then, the macro morphology, microstructure, phase composition and coating element distribution of the coatings with different proportions were compared and analyzed by means of scanning electron microscopy (SEM), EDS energy spectrometer, D/max-2500/PC X-ray diffractometer (XDR) and other test methods. The hardness of the coating was tested by Qness Vickers microhardness tester and the variation law of the microhardness of the cross section of the cladding sample was analyzed. The friction and wear properties of the coatings with different material components were studied by MMU-5G end friction and wear tester. The results show that the cladding layer of the specimen forms a good metallurgical bonding with the substrate. The microstructure of the cladding layer is mainly dendritic structure and block structure. The main phases of each cladding layer all contain TiC, and as the content of ternary ceramic powder increases, the content of MC also increases. When the carbide mixed powder is 15% (mass fraction), Hf0.8Ta0.2Fe2 ternary alloy phase is detected in the cladding layer. When the content of ternary ceramic powder is 10% (mass fraction), the cladding grain is the smallest, the average hardness of the coating layer is the highest, and the average hardness is about 763.43 HV, 2.29 times the hardness of the substrate. When the content of ternary ceramic powder is 5% (mass fraction), the coating has the best wear resistance, and the relative wear resistance is 25%.

Cite this article

FU Yuming, MA Shunxin, LIU Shaofeng, et al . Microstructure and Properties of Laser Cladding Hard Composite Coating on TC4 Surface[J]. Journal of South China University of Technology(Natural Science), 2024 , 52(3) : 10 -17 . DOI: 10.12141/j.issn.1000-565X.230061

References

1 高敬,姚丽 .国内外钛合金研究发展动态[J].世界有色金属2001(2):4-7.
  GAO Jing, YAO Li .Research and development of titanium alloy at home and abroad[J].World Non-Ferrous Metals2001(2):4-7.
2 张海云,张金,朱磊,等 .WC含量对激光熔覆TC4涂层组织及性能的影响[J].热加工工艺202251(8):83-87.
  ZHANG Haiyun, ZHANG Jin, ZHU Lei,et al .Effects of WC content on microstructure and properties of TC4 compositePrepared by laser cladding[J].Hot Working Technology202251(8):83-87.
3 赵永庆,葛鹏,辛社伟 .近五年钛合金材料研发进展[J].中国材料进展202039(Z1):527-534.
  ZHAO Yongqing, GE Peng, XIN Shewei .Progresses of R&D on Ti-Alloy materials in recent 5 years[J].Materials China202039(Z1):527-534.
4 柯金,刘秀波,庄宿国,等 .Ti6Al4V合金激光熔覆NiMoSi复合涂层的高温抗氧化性能[J].中国表面工程201831(6):109-117.
  KE Jin, LIU Xiubo, ZHUANG Suguo,et al .High temperature oxidation resistance of NiMoSi composite coatings on Ti6Al4V Alloy by laser cladding[J].China Surface Engineering201831(6):109-117.
5 谭金花,孙荣禄,牛伟,等 .TC4合金激光熔覆材料的研究现状[J].材料导报202034(15):15132-15137.
  TAN Jinhua, SUN Ronglu, NIU Wei,et al .Research status of TC4 alloy laser cladding Materials[J].Materials Reports202034(15):15132-15137.
6 菅丽娜,张凌云,于荣莉,等 .钛合金表面激光熔敷Cr(13)Ni5Si2基金属硅化物涂层组织与耐磨性[J].稀有金属材料与工程200534(6):936-939.
  JIAN Lina, ZHANG Lingyun, YU Rongli,et al .Microstructure and wear resistance of laser clad Cr13Ni5Si2-Based metal silicide coating on titanium alloy[J].Race Metal Materials and Engineering200534(6):936-939.
7 林熙 .TC4表面激光熔覆耐磨涂层组织结构及性能的研究[D].天津:天津工业大学,2018.
8 易家,彭如恕 .TC4钛合金表面激光合金化涂层的组织与耐磨性能[J].金属热处理202045(2):225-230.
  YI Jia, PENG Rushu .Microstructure and wear resistance of laser alloying coating on TC4 titanium alloy surface[J].Heat Treatment of Metals202045(2):225-230.
9 孟祥军,沈颖,张少瑜,等 .Ti6Al4V合金激光熔覆Co-Ti3SiC2复合涂层的组织和摩擦学性能[J].金属热处理202146(12):199-203.
  MENG Xiangjun, SHEN Ying, ZHANG Shaoyu,et al .Microstructure and tribological properties of laser clad Co-Ti3SiC2 composite coating on Ti6A4V alloy[J].Heat Treatment of Metals202146(12):199-203.
10 MORIDI A, HASSANI-GANGARAJ S M, GUAGLIANO M,et al .Cold spray coating:review of materialsystems and fu-tureperspectives[J].Surface Engineering201430(6):369-395.
11 赵海涛,付洪宇 .激光熔覆数值模拟技术发展现状及应用[J].沈阳理工大学学报202140(3):58-63,73.
  ZHAO Haitao, FU Hongyu .The development and application of laser cladding numerical simulation technology[J].Journal of Shenyang Ligong University202140(3):58-63,73.
12 李玉海,王震,赵晖,等 .铜合金激光表面强化研究进展[J].沈阳理工大学学报201938(6):22-27.
  LI Yuhai, WANG Zhen, ZHAO Hui,et al .Research progress on laser surface strengthening of copper alloy[J].Journal of Shenyang Ligong University201938(6):22-27.
13 RAHMANI H, RASTEGARI S, MIRDAMADI S .Effective pa-rameters on microstructure and properties of EB-PVD NiCrAlY coating[J].Surface Engineering201531(2):156-165.
14 TIAN Y S, CHEN C Z, WANG D Y,et al .Laser surface alloying of pure titanium with TiN-B-Si-Ni mixed powders[J].Applied Surface Science2005250(1):223-227.
15 TIAN Y S, CHAN C Z, CHEN L X,et al .Microstructures and wear properties of composite coatings produced by laser alloying of Ti-6Al-4V with graphite and silicon mixed powders[J].Materials Letters200660(1):109-113.
16 王东生,田宗军,沈理达,等 .钛合金激光表面改性技术研究现状[J].激光与光电子学进展200845(6):24-32.
  WANG Dongsheng, TIAN Zongjun, SHEN Lida,et al .Research states of laser surface modification technology on titanium alloys[J].Laser & Optoelectronics Progress200845(6):24-32.
17 LI J N, CHEN C Z, ZONG L .Microstructure characteristics of Ti3Al/TiC ceramic layer deposited by laser cladding[J].International Journal of Refractory Metals and Hard Materials201129(1):49-53.
18 LI J, CHEN C, SQUARTINI T,et al .A study on wear resistance and microcrack of the Ti3Al/TiAl+TiC ceramic layer deposited by laser cladding on Ti-6Al-4V alloy[J].Applied Surface Science2010257(5):1550-1555.
19 WANG H M, LIU Y F .Microstructure and wear resistance of laser clad Ti5Si3/NiTi2 intermetallic composite coating on titanium alloy[J].Materials Science and Engineering:A2002338(1):126-132.
20 SONG R, LI J, SHAO J Z,et al .Microstructural evolution and wear behaviors of laser cladding Ti2Ni/α(Ti) dual-phase coating reinforced by TiB and Ti C[J].Applied Surface Science2015355:298-309.
21 刘建弟,张述泉,王华明 .激光熔覆WC颗粒增强复合涂层的组织及耐磨性[J].中国有色金属学报201222(9):2600-2607.
  LIU Jian-di, ZHANG Shu-quan, WANG Hua-ming .Microstructure and wear resistance of laser cladding WC particles reinforced composite coatings[J].The Chinese Journal of Nonferrous Metals201222(9):2600-2607.
22 王璐,胡树兵,单炜涛,等 .激光熔覆NiCrMn-WC复合涂层的组织与耐磨性[J].中国有色金属学报201424(1):145-151.
  WANG Lu, HU Shu-bing, SHAN Wei-tao,et al .Microstructure and wear resistance of laser cladding NiCrMn-WC composite coatings[J].The Chinese Journal of Nonferrous Metals201424(1):145-151.
23 ZHOU S, LEI J, DAI X,et al .A comparative study of the structure and wear resistance of NiCrBSi/50 wt% WC composite coatings by laser cladding and laser induction hybrid cladding[J].International Journal of Refractory Metals and Hard Materials201660:17-27.
24 LUO X, LI J, LI G J .Effect of NiCrBSi content on microstructural evolution,cracking susceptibility and wear behaviors of laser cladding WC/Ni-NiCrBSi composite coatings[J].Journal of Alloys and Compounds2015626:102-111.
25 冯进宇,肖华强,肖易,等 .TC4表面激光熔覆Ti-Al-(C,N)复合涂层的组织与力学性能[J].中国激光202249(2):165-173.
  FENG Jinyu, XIAO Huaqiang, XIAO Yi,et al .Microstructure and mechanical properties of laser cladded Ti-Al-(C,N) composite coating on TC4 surface[J].Chinese Journal of Lasers202249(2):165-173.
26 秦阳,闫华,高秋实,等 .TC4表面激光熔覆原位合成Ti3SiC2/Ni基涂层的组织与耐磨性能[J].有色金属工程20199(4):34-40.
  QIN Yang, YAN Hua, GAO Qiushi,et al .Microstructure and wear resistance of in-situ synthesized Ti3SiC2/Ni-based coating by laser cladding on titanium alloy[J].Nonferrous Metals Engineering20199(4):34-40.
27 覃鑫,祁文军,左小刚 .TC4钛合金表面激光熔覆NiCrCoAlY-Cr 3C2复合涂层的摩擦和高温抗氧化性能[J].材料工程202149(12):107-114.
  QIN Xin, QI Wen-jun, ZUO Xiao-gang .Friction and high temperature oxidation resistance of laser cladding NiCrCoAlY-Cr3C2 composite coating on TC4 titanium alloy[J].Journal of Materials Engineering202149(12):107-114.
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