Environmental Science & Technology

Review on Application of Molecular Sieve to Denitration Catalysts for Low-Temperature NH3 -SCR

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  • 1. School of Environment and Energy,South China University of Technology,Guangzhou 510006,Guangdong,China;2. The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters,Ministry of Education,South China University of Technology,Guangzhou 510006,Guangdong,China
喻成龙(1988-),男,博士生,主要从事空气污染物催化净化研究. E-mail: chenglongyu888@163. com

Received date: 2014-08-05

  Revised date: 2014-10-08

  Online published: 2015-02-10

Supported by

Supported by the National Natural Science Foundation of China(NSFC)(20977034,51478191)

Abstract

Low-temperature NH3 -SCR is an efficient technology with high economic value and broad application prospect for transforming NOx into N2 below 200 ℃. Great attention has been paid worldwide to develop low-temperature SCr denitration catalysts with high activity and strong resistance to sulfur dioxide and water,which is also crucial for the development and application of low-temperature SCr technologies. Molecular sieves are of ex-cellent adsorption performance,suitable surface acidity,good shape selectivity and flexibility,as well as the capa-bility of introducing transition metal elements. This paper reviews the research progress of molecular sieves used in denitration catalysts for low-temperature NH3 -SCR,and emphasizes the low-temperature selective catalytic reduction performance,the sulfur dioxide and water resistance,as well as the reaction mechanism of ZSM-5,SAPO-34,SBA-15,MCM-41 and beta molecular sieve. Moreover,the application of calculating simulation to the design of molecular sieve catalysts is introduced,some problems existing in the application of molecular sieves to low-tempe-rature NH3-SCR are analyzed,and the future research trend is also pointed out.

Cite this article

Yu Cheng-long Huang Bi-chun Yang Ying-xin . Review on Application of Molecular Sieve to Denitration Catalysts for Low-Temperature NH3 -SCR[J]. Journal of South China University of Technology(Natural Science), 2015 , 43(3) : 143 -150 . DOI: 10.3969/j.issn.1000-565X.2015.03.021

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