Journal of South China University of Technology (Natural Science Edition) ›› 2015, Vol. 43 ›› Issue (3): 143-150.doi: 10.3969/j.issn.1000-565X.2015.03.021

• Environmental Science & Technology • Previous Articles    

Review on Application of Molecular Sieve to Denitration Catalysts for Low-Temperature NH3 -SCR

Yu Cheng-long1 Huang Bi-chun1,2 Yang Ying-xin1   

  1. 1. School of Environment and Energy,South China University of Technology,Guangzhou 510006,Guangdong,China;2. The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters,Ministry of Education,South China University of Technology,Guangzhou 510006,Guangdong,China
  • Received:2014-08-05 Revised:2014-10-08 Online:2015-03-25 Published:2015-02-10
  • Contact: 黄碧纯(1966-),女,教授,主要从事大气污染控制研究. E-mail:cebhuang@scut.edu.cn
  • About author:喻成龙(1988-),男,博士生,主要从事空气污染物催化净化研究. E-mail: chenglongyu888@163. com
  • Supported by:
    Supported by the National Natural Science Foundation of China(NSFC)(20977034,51478191)

Abstract: Low-temperature NH3 -SCR is an efficient technology with high economic value and broad application prospect for transforming NOx into N2 below 200 ℃. Great attention has been paid worldwide to develop low-temperature SCr denitration catalysts with high activity and strong resistance to sulfur dioxide and water,which is also crucial for the development and application of low-temperature SCr technologies. Molecular sieves are of ex-cellent adsorption performance,suitable surface acidity,good shape selectivity and flexibility,as well as the capa-bility of introducing transition metal elements. This paper reviews the research progress of molecular sieves used in denitration catalysts for low-temperature NH3 -SCR,and emphasizes the low-temperature selective catalytic reduction performance,the sulfur dioxide and water resistance,as well as the reaction mechanism of ZSM-5,SAPO-34,SBA-15,MCM-41 and beta molecular sieve. Moreover,the application of calculating simulation to the design of molecular sieve catalysts is introduced,some problems existing in the application of molecular sieves to low-tempe-rature NH3-SCR are analyzed,and the future research trend is also pointed out.

Key words: selective catalytic reduction, low-temperature denitration, catalyst, molecular sieves, transition metal