Journal of South China University of Technology (Natural Science Edition) ›› 2009, Vol. 37 ›› Issue (8): 132-139.

• Materials Science & Technology • Previous Articles     Next Articles

Influence of Doped Chloride Ions on Steel Corrosion and Solidification of Chloride Ions by Different Materials

Xie Yah  Wu Xiao-mei  Fan Yue-ming  Yu Qi-jun  Chen Ying-yun   

  1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2009-01-07 Revised:2009-02-25 Online:2009-08-25 Published:2009-08-25
  • Contact: 谢燕(1982-),女,博士生,主要从事水泥混凝土材料的研究. E-mail:xieyanscut@gmail.com
  • About author:谢燕(1982-),女,博士生,主要从事水泥混凝土材料的研究.
  • Supported by:

    广州市环保局科技攻关项目(B09-B2070040)

Abstract:

Based on the half-cell potential and anodic polarization curves obtained via the fast steel corrosion test, the influences of different chloride salts and chlorin-containing materials on the steel corrosion are investigated, and the solidification of doped chloride ions by different materials is analyzed. The results indicate that  the influ- ence of CaCl2 on steel corrosion is more serious than that of NaCl as steel corrosion may occur at lower total chloride and free-chloride contents when it is doped with CaCl2;  buildups may lead to steel corrosion at a content of more than 20% ;  bottom ash does not induce steel corrosion due to its low chloride content;  the addition of cement, slag and fly ash with high effective aluminate content effectively solidifies chloride ions and reduces the steel corrosion; and  anodic polarization curves describe the steel corrosion better than half-cell potential when cement is mixed with admixtures and other compositions.

Key words: internal doping, chloride ion, steel corrosion, solidification