Preparation of Amphoteric Tapioca Carboxylic Ester Starch and Corresponding Mechanism

Journal of South China University of Technology (Natural Science Edition) ›› 2008, Vol. 36 ›› Issue (11): 68-73.

• Chemistry & Chemical Engineering • Previous Articles Next Articles

Preparation of Amphoteric Tapioca Carboxylic Ester Starch and Corresponding Mechanism

Luo Ming-hui¹ Lu En-xi¹ Zhang Ben-shan²

1. Key Laboratory of Enhanced Heat Transfer and Energy Conservation of the Ministry of Education, South China University of Technology, Guangzhou 510640, Guangdong, China; 2. School of Light Industry and Food Sciences, South China University of Technology, Guangzhou 510640, Guangdong, China

Received:2007-11-19 Revised:2008-03-03 Online:2008-11-25 Published:2008-11-25
Contact: 罗明辉（1973-），男，博士生，主要从事工业淀粉的研究． E-mail:luomh2002@163．com
About author:罗明辉（1973-），男，博士生，主要从事工业淀粉的研究．
Supported by:
国家科技支撑计划项目（2006BAD27804）

Abstract

Abstract:

Amphoteric tapioca starch with carboxyl groups was produced via crosslinking, oxidation and etherization reactions. The product was then characterized by means of SEM, XRD and colloid titration, with the preparation mechanism being also investigated. The results indicate that the degrees of substitution （DS） of carboxyl groups and quaternary ammonium groups respectively reach 0. 018 and 0. 033, that the viscosity of the product with a content of 6% is 258mPa· s at 50℃, and that there exists a competition between the carboxyl groups and the negative oxygen ions. It is also revealed from the viewpoint of micromechanism that the modification reactions has no effect on the crystalline structure of the starch.

Key words: amphoteric starch, viscosity, carboxyl group, crosslinking, oxidation

Luo Ming-hui Lu En-xi Zhang Ben-shan . Preparation of Amphoteric Tapioca Carboxylic Ester Starch and Corresponding Mechanism[J]. Journal of South China University of Technology (Natural Science Edition), 2008, 36(11): 68-73.

[1]	HUANG Huihua, TANG Lu, LIU Yushan, et al. Preparation of Pineapple Peel Cellulose Nanocrystals and Their Environment Stability in Pickering Emulsions [J]. Journal of South China University of Technology(Natural Science Edition), 2022, 50(8): 1-11.
[2]	JIANG Jihai DU Boran ZHANG Jian. Application and Technology Prospects of Hydrodynamic-Magnetic Compound Support for Axial Piston Pump [J]. Journal of South China University of Technology(Natural Science Edition), 2021, 49(2): 88-98,109.
[3]	LIU Shumei CHEN Jiajun WU Yancheng ZHAO Jianqing. Effect Of Side Group Substitution On The Properties Of Cardo-type Polyimides Containing Hydroxyl Groups [J]. Journal of South China University of Technology(Natural Science Edition), 2021, 49(12): 16-22.
[4]	CHEN Yongzhi, YUAN Zhongling, ZHANG Min'an, et al. On Optimized Removal of Nitrogen and Carbon with Anaerobic Ammonium Oxidation Based on Matching Multiple Factors #br# and Response Surface Method [J]. Journal of South China University of Technology (Natural Science Edition), 2021, 49(11): 69-79.
[5]	HU Songqing LI Wang CHEN Yu HOU Yi. Expression of Wheat Endoplasmic Reticulum Oxidoreductin 1 in Pichia pastoris [J]. Journal of South China University of Technology (Natural Science Edition), 2019, 47(8): 57-63,70.
[6]	LOU Wenyong ZHAO Ying PENG Fei. Asymmetric Oxidation of Ｒacemic 1-Phenyl-1，2-Ethanediol Using Immobilized Kurthia gibsonii SC0312 Cells in DESs-Containing System [J]. Journal of South China University of Technology (Natural Science Edition), 2019, 47(11): 62-70.
[7]	XU Defeng MA Zhonghua ZHAO Mouming ZHANG Ting SU Guowan. Effect of Four Kinds Food-Derived Peptides on the Oxidative and Inflammatory System in Photoaging Skin of SD Rats [J]. Journal of South China University of Technology(Natural Science Edition), 2018, 46(6): 87-92.
[8]	LUO Chao FAN Shuanshi YAN Ying ZHANG Huiping. A Study of Microfibrous Entrapped Cu/Cr/Ag Impregnated Carbons for CO Oxidation [J]. Journal of South China University of Technology (Natural Science Edition), 2018, 46(2): 88-92,101.
[9]	XIONG Jian XIE Liping ZHANG Ting LIANG Min YUAN Erdong REN Jiaoyan. Interaction Between Memory-Enhancing Chinese Herbal Medicine and Walnut Peptides#br# [J]. Journal of South China University of Technology(Natural Science Edition), 2018, 46(11): 1-8.
[10]	GAO Qun-yu DAI Gui-fang LI Hang WU Lei. Effects of Oxidation and Etherification Dual-Modification on Physicochemical Properties of Corn Starch [J]. Journal of South China University of Technology (Natural Science Edition), 2017, 45(9): 47-52.
[11]	YANG Yi ZHANG Hui-ping YAN Ying. Catalytic Wet Peroxide Oxidation of Phenol on CeO₂ -ZSM-5 Fixed Bed Reactor [J]. Journal of South China University of Technology (Natural Science Edition), 2017, 45(6): 117-123,130.
[12]	ZHANG Qin WU Rui-qi AOYAMA Hisayuki. Performance Analysis and Experiment Investigation of Transfer Printing pL-Class Fluid Distribution Approach [J]. Journal of South China University of Technology (Natural Science Edition), 2017, 45(5): 9-15.
[13]	WU Xiao-mei GAO Qiang LIU Sha-sha HUANG Ding-ce TIAN Ya-po FAN Yue-ming. Determination of Rheological Parameter of Mortar by Using a Cone-Based Rheometer [J]. Journal of South China University of Technology (Natural Science Edition), 2017, 45(11): 86-91.
[14]	Li Kang Li Wen-fang Zhang Guo-ge Duan Qi. Micro Arc Oxidation and Layer Characteristics of Binary Al-Si Alloys of Different Si Content [J]. Journal of South China University of Technology (Natural Science Edition), 2015, 43(7): 1-7.
[15]	Cheng Wei-wei Liu Guo-qin Liu Xin-qi Wang Xue-de Lu Xiao-zhu. Investigation into Preparation Technology of Epoxidized Soybean Oil via Phase-Transfer Catalysis [J]. Journal of South China University of Technology (Natural Science Edition), 2015, 43(11): 23-29.

Preparation of Amphoteric Tapioca Carboxylic Ester Starch and Corresponding Mechanism

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments