Journal of South China University of Technology (Natural Science Edition) ›› 2006, Vol. 34 ›› Issue (10): 40-43.

• Materials Science & Technology • Previous Articles     Next Articles

Synthesis and Adsorption Property of Cross-Linked Chitosan Vanillin Schif Base by Formaldehyde Under Microwave Radiation

Ge Hua-ca  Ma Zhi-min  Zheng Da-feng  Ge Jun-wei   

  1. School of Chemical Science,South China Univ .of Tech.,Guangzhou 5 10640,Guangdong,China
  • Received:2005-07-15 Online:2006-10-25 Published:2006-10-25
  • Contact: 葛华才(1963-),男,博士,副教授,主要从事精细化工和化学动力学研究 E-mail:chhcge@scut.edu.cn
  • About author:葛华才(1963-),男,博士,副教授,主要从事精细化工和化学动力学研究
  • Supported by:

    国家自然科学基金资助项目(50673027)

Abstract:

A cross.linked chitosan vanillin Schif base was synthesized by formaldehyde under microwave radiation,whose structure was then characterized by means of IR and XRD.The solubility of the product·in acidic solutions was also compared with that of chitosan vanillin Schif base using UV absorption spectrum.The adsorption experi-ment showed that.as compared with chitosan vanillin schif base and cross.linked chitosan by form aldehyde,the
product is of different adsorption capability for some metal ions.Moreover.as the product possesses excellent selec-tive adsorption for Cu2+ and is insoluble in acid conditions.it can be used as a selective adsorbent of Cu2+ .

Key words: chitosan, modification, microwave radiation, adsorption