Preparation of 5-Hydroxymethylfurfural from Glucose Catalyzed by Cation Exchange Resin and Al2O3

doi:10.3969/j.issn.1000-565X.2010.11.013

Journal of South China University of Technology (Natural Science Edition) ›› 2010, Vol. 38 ›› Issue (11): 69-73.doi: 10.3969/j.issn.1000-565X.2010.11.013

• Chemistry & Chemical Engineering • Previous Articles Next Articles

Preparation of 5-Hydroxymethylfurfural from Glucose Catalyzed by Cation Exchange Resin and Al₂O₃

Lin Lu Chen Tian-ming

State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China

Received:2010-03-26 Revised:2010-05-14 Online:2010-11-25 Published:2010-11-25
Contact: 林鹿（1962-），男，教授，博士生导师，主要从事生物质能源与高附加值化工产品开发的研究． E-mail:lclulin@scut．edu．cn
About author:林鹿（1962-），男，教授，博士生导师，主要从事生物质能源与高附加值化工产品开发的研究．
Supported by:
国家自然科学基金资助项目（50776035）; 国家“十一五”科技支撑计划项目（2007BAD34B01）; 国家“863”计划项目（2007AA05Z408）; 国家自然科学基金-广东联合基金重点项目（U0733001）

Abstract

Abstract:

5-Hydroxymethylfurfural（5-HMF） was prepared from glucose,with strong-acid cation exchange resin 732 and Al₂O₃as the catalysts and with DMSO as the reaction medium.Then,the corresponding reaction process was investigated,and the stabilities of both the resin and Al₂O₃ were analyzed.The results show that DMSO accele-rates the catalytic conversion of glucose,that the glucose conversion,the 5-HMF yield and the selectivity respectively reach 90.19%,44.53% and 49.37% after a 12-h reaction at 130 ℃ with an initial glucose content（mass fraction） of 10%,and that resin 732 and Al₂O₃ keep stable even after being used for many times.

Key words: glucose, 5-Hydroxymethylfurfural, strong-acid cation exchange resin, alumina, catalysis

Lin Lu Chen Tian-ming. Preparation of 5-Hydroxymethylfurfural from Glucose Catalyzed by Cation Exchange Resin and Al₂O₃[J]. Journal of South China University of Technology (Natural Science Edition), 2010, 38(11): 69-73.

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Preparation of 5-Hydroxymethylfurfural from Glucose Catalyzed by Cation Exchange Resin and Al₂O₃

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