华南理工大学学报(自然科学版) ›› 2012, Vol. 40 ›› Issue (10): 146-151.doi: 1000-565X(2012)10-0146-06

• 校庆专辑 • 上一篇    下一篇

CO2饱充流速对碳酸钙形态及吸附能力的影响

于淑娟 喻佩 扶雄 潘润全 赵毅   

  1. 华南理工大学 轻工与食品学院,广东 广州 510640
  • 收稿日期:2012-08-06 修回日期:2012-07-27 出版日期:2012-10-25 发布日期:2012-09-01
  • 通信作者: 于淑娟(1955-) ,女,教授,博士生导师,主要从事制糖工程、碳水化合物分子修饰研究. E-mail:shujuanyu8@gmail.com
  • 作者简介:于淑娟(1955-) ,女,教授,博士生导师,主要从事制糖工程、碳水化合物分子修饰研究.
  • 基金资助:

    国家“十二五”科技支撑计划项目( 2011BAE16B02) ; 广东省教育部产学研结合项目( 2011B090400361)

Effects of CO2 Flow Rate on Morphology and Adsorption Capacity of CaCO3

Yu Shu-juan  Yu Pei  Fu Xiong  Pan Run-quan  Zhao Yi   

  1. School of Light Industry and Food Sciences,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2012-08-06 Revised:2012-07-27 Online:2012-10-25 Published:2012-09-01
  • Contact: 于淑娟(1955-) ,女,教授,博士生导师,主要从事制糖工程、碳水化合物分子修饰研究. E-mail:shujuanyu8@gmail.com
  • About author:于淑娟(1955-) ,女,教授,博士生导师,主要从事制糖工程、碳水化合物分子修饰研究.
  • Supported by:

    国家“十二五”科技支撑计划项目( 2011BAE16B02) ; 广东省教育部产学研结合项目( 2011B090400361)

摘要: 通过扫描电子显微镜( SEM) 、聚焦光束反射测量仪( FBRM) 监测碳酸法饱充体系中碳酸钙颗粒形态、生成速度和粒径的变化,同时以色值、还原糖含量和简纯度为指标,监测CO2饱充流速对碳酸钙颗粒的影响,研究影响碳酸钙颗粒吸附非糖分的因素.实验结果表明: 在较低的CO2饱充流速下,碳酸钙颗粒为表面结构紧密的立方体,而在较高的CO2饱充流速下,碳酸钙颗粒为表面呈层状的棒形结构; FBRM 在线观测发现体系固体颗粒弦长主要在1 ~100μm 范围内,并且随着CO2饱充流速的增大,体系颗粒粒径向大尺寸范围变化;快速饱充能保护还原糖不受破坏;通入等量CO2时,随CO2饱充流速的增大,清净汁色值降低,简纯度升高; CO2饱充流速对无机阳离子K+、Na+、Ca2+、Mg2+的吸附影响不大; 因此在适宜的CO2饱充流速( 300 ~900mL/min) 范围内,快速饱充是一项切实可行的澄清技术.

关键词: 糖汁清净, 碳酸钙, 吸附, 饱充, 色值, 简纯度

Abstract:

In order to study the factors that influence the adsorption of non-sugar by calcium carbonate during the process of carbonation in multi-component syrup and to clarify the effects of CO2 flow rates on CaCO3 particles,the morphologies,formation rate and sizes of the CaCO3 particles were characterized by means of SEM and FBRM. Moreover,the color value,the content of reducing sugar and the apparent purity were determined as the indexes. Experimental results show that ( 1) the CaCO3 particles are cube-shaped at a lower CO2 flow rate while they are rod-like at a higher flow rate; ( 2) the CaCO3 particle chord lengths obtained by using an on-line FBRM are within a range of 1 ~ 100 μm,and the range becomes wider with the increase of the CO2 flow rate; ( 3) fast carbonation can protect the reducing sugar from destruction; ( 4) when the CO2 content is constant,with the increase of the CO2 flow rate,the color value of clarified juice decreases while the corresponding apparent purity improves; ( 5) the CO2 flow rate has little influence on the adsorption of the inorganic cations of K + ,Na + ,Ca2 + and Mg2 + ; and ( 6) within an appropriate flow rate range of 300~900mL /min,fast carbonation proves to be a feasible clarification technology.

Key words: sugar juice clarification, calcium carbonate, adsorption, carbonation, color value, apparent purity

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