华南理工大学学报(自然科学版) ›› 2013, Vol. 41 ›› Issue (12): 6-11,23.doi: 10.3969/j.issn.1000-565X.2013.12.002

• 化学化工、能源 • 上一篇    下一篇

相对分子质量对氨基磺酸系陶瓷浆料分散剂性能的影响

庞煜霞1 高菲1 邓永红1 郭素芳1 邱学青1,2†   

  1. 1.华南理工大学 化学与化工学院,广东 广州 510640; 2.华南理工大学 制浆造纸工程国家重点实验室,广东 广州 510640
  • 收稿日期:2013-06-25 修回日期:2013-08-12 出版日期:2013-12-25 发布日期:2013-11-19
  • 通信作者: 邱学青(1965-),男,教授,博士生导师,主要从事木质素的资源化利用研究 E-mail:cexqqiu@scut.edu.cn
  • 作者简介:庞煜霞(1975-),女,博士,副研究员,主要从事木质素磺酸盐系精细化学品的开发研究.E-mail:ceyxpang@scu.tedu.cn
  • 基金资助:

    国家国际科技合作专项项目(2013DFA41670);广东省科技计划项目(2010A080804020, 2012B010200021)

Effect of Relative Molecular Mass of Amino- Sulfonic Acid- Based Dispersants on Performances of Ceramic Slurry

Pang Yu- xia1 Gao Fei1 Deng Yong- hong1 Guo Su- fang1 Qiu Xue- qing1,2   

  1. 1.School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China;2.State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2013-06-25 Revised:2013-08-12 Online:2013-12-25 Published:2013-11-19
  • Contact: 邱学青(1965-),男,教授,博士生导师,主要从事木质素的资源化利用研究 E-mail:cexqqiu@scut.edu.cn
  • About author:庞煜霞(1975-),女,博士,副研究员,主要从事木质素磺酸盐系精细化学品的开发研究.E-mail:ceyxpang@scu.tedu.cn
  • Supported by:

    国家国际科技合作专项项目(2013DFA41670);广东省科技计划项目(2010A080804020, 2012B010200021)

摘要: 通过超滤获得氨基磺酸系分散剂 ASP 的 5 种不同相对分子质量范围的级分,研究了不同级分对陶瓷浆料应用性能的影响,并结合黑泥颗粒上的吸附量及Zeta 电位探讨其原因.研究发现:掺高相对分子质量级分(截留相对分子质量 >10000)的陶浆流出时间短,流动性和分散性好,触变性小;ASP 相对分子质量的增加能提高其在黑泥颗粒表面的吸附量,使颗粒间的 Zeta 电位和空间位阻增大,从而能更好地分散;单一 ASP 超滤级分的分散性能均不如未分级的 ASP,说明当不同相对分子质量 ASP 级分配合使用时,陶瓷浆体的性能达到最优,这可能与低、高相对分子质量 ASP 级分在陶瓷颗粒表面穿插多层吸附使得吸附量提高有关.

关键词: 陶瓷浆体, 氨基磺酸系分散剂, 相对分子质量, 吸附, 超滤

Abstract:

Five fractions of amino- sulfonic acid- based dispersant ASP with different relative molecular mass wereobtained via ultrafiltration,and their influences on the application performances of ceramic slurry were analyzed,with the corresponding mechanism being explored by analyzing the adsorption amount and the Zeta potential of thesefive ASP fractions on black mud particles.The results indicate that (1) the ceramic slurries added ASP fractionswith high relative molecular mass (more than 10000) are of less outflow time,high fluidity,dispersion andlow thixotropy; (2) the adsorption amount of ASP on black mud particles may increase with the relative molecularmass of ASP,thus improving the Zeta potential between black mud particles and enhancing the steric effect,whichmakes ceramic particles disperse better; (3) ASP without ultrafiltration possesses better dispersion property thaneach ultrafiltrated fraction,which means that the ASP fractions with different relative molecular mass work together toendow the ceramic slurry with best performance.This may be related to the improvement of adsorption amount due tothe multi- layer adsorption of ASP fractions with different relative molecular mass on the ceramic particle surface.

Key words: ceramic slurry, amino- sulfonic acid- based dispersant, relative molecular mass, adsorption, ultrafiltration

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