华南理工大学学报(自然科学版) ›› 2010, Vol. 38 ›› Issue (9): 46-51.doi: 10.3969/j.issn.1000-565X.2010.09.009

• 化学化工 • 上一篇    下一篇

高得率竹浆抽出物及其对H2O2漂白的影响

梁辰 詹怀宇 李兵云 付时雨   

  1. 华南理工大学 制浆造纸工程国家重点实验室, 广东 广州 510640
  • 收稿日期:2009-12-24 修回日期:2010-03-23 出版日期:2010-09-25 发布日期:2010-09-25
  • 通信作者: 梁辰(1984-),男,博士生,主要从事制浆化学与生物化学研究. E-mail:licee@163.com
  • 作者简介:梁辰(1984-),男,博士生,主要从事制浆化学与生物化学研究.
  • 基金资助:

    国家“973”计划预研项目(2006CB70861.4)

Extractives of High-Yield Bamboo Pulp and Their Effects on H2O2 Bleaching

Liang Chen  Zhan Huai-yu  Li Bing-yun  Fu Shi-yu   

  1. State Key Laboratory of Pulp and Paper Engineering,South China Univevsity of Technology,Guangzhou 510640,Guangdong,China
  • Received:2009-12-24 Revised:2010-03-23 Online:2010-09-25 Published:2010-09-25
  • Contact: 梁辰(1984-),男,博士生,主要从事制浆化学与生物化学研究. E-mail:licee@163.com
  • About author:梁辰(1984-),男,博士生,主要从事制浆化学与生物化学研究.
  • Supported by:

    国家“973”计划预研项目(2006CB70861.4)

摘要: 研究了高得率竹浆——慈竹磺化化机浆(SCMP)的抽出物及其对过氧化氢漂白的影响。结果表明:采用苯醇、二氯甲烷、甲醇3种抽提方法,慈竹SCMP的抽出物含量均较低,抽出物中主要成分是脂肪酸类和甾醇类物质,以及部分在紫外区330 nm左右产生吸收的物质;经3种抽提方法抽提处理后,漂白纸浆白度均可提高6%以上,苯醇抽提后高达9%ISO;抽提处理后过氧化氢漂白浆偏黄现象减轻,最大下降了37.3%,返黄值下降,最大下降了65.8%.

关键词: 竹子, 高得率浆, 溶剂抽提, 抽出物, 过氧化氢, 漂白, 光学性能

Abstract:

This paper deals with the extractives of high-yield Neosinocalamus sulfonated chemimechanical pulp(SCMP) and their effects on the hydrogen peroxide bleaching.The results show that the extractives from Neosinocalamus SCMP in benzene-alcohol,dichloromethane and methanol are all in low content,that the extractives mainly contain fatty acids and steroids,as well as some substances producing UV absorption at about 330nm,that the brightness of peroxide-bleached pulp after the extraction increases by more than 6%,and by 9%ISO especially after the benzene-alcohol extraction,and that the yellowish phenomenon of the bleached pulp lightens to a degree of 37.3% at most and the heat-induced yellowing value decreases by 65.8% at most.

Key words: bamboo, high yield pulp, solvent extraction, extractives, hydrogen peroxide, bleaching, optical pro-perties