华南理工大学学报(自然科学版) ›› 2008, Vol. 36 ›› Issue (7): 11-15.

• 化学化工 • 上一篇    下一篇

赤桉木材微/纳米粒子的溶出规律

彭万喜 武书彬   

  1. 华南理工大学 制浆造纸工程国家重点实验室, 广东 广州 510640
  • 收稿日期:2007-10-08 修回日期:2008-01-08 出版日期:2008-07-25 发布日期:2008-07-25
  • 通信作者: 武书彬(1965-),男,博士,教授,主要从事生物质化学与化工、二次纤维利用新技术等的研究. E-mail:shubinwu@scut.edu.cn
  • 作者简介:彭万喜(1974-),男,博士后,副教授,主要从事木材抽提物资源开发与利用的研究.E-mail:pengwanxi@163.com.
  • 基金资助:

    国家973计划资助项目(2007CB210201);国家自然科学基金资助项目(20576043);中国博士后科学基金资助项目(20070420776)

Leaching Laws of Micro/Nano Particles from ucalyptus camaldulensis Wood

Peng Wan-xi  Wu Shu-bin   

  1. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2007-10-08 Revised:2008-01-08 Online:2008-07-25 Published:2008-07-25
  • Contact: 武书彬(1965-),男,博士,教授,主要从事生物质化学与化工、二次纤维利用新技术等的研究. E-mail:shubinwu@scut.edu.cn
  • About author:彭万喜(1974-),男,博士后,副教授,主要从事木材抽提物资源开发与利用的研究.E-mail:pengwanxi@163.com.
  • Supported by:

    国家973计划资助项目(2007CB210201);国家自然科学基金资助项目(20576043);中国博士后科学基金资助项目(20070420776)

摘要: 采用单因素试验法,分析赤桉木材缈纳米粒子在索氏抽提、超声抽提、冷冻抽提、激光等离子抽提中的溶出规律.结果表明:在索氏抽提过程中,溶出量随赤桉木片抽提时间的延长而增大;在抽提1.5,3.5和4.0h时溶出粒子中有数量极少的粒径分别为4150~5560nm、4150~5560nm、1110~6440nm的粒子,其体积分数分别为0.3%,0.3%和2.6%,但足以对木材渗透产生屏障、对制浆产生树脂障碍;超声、冷冻预处理、激光等离子在抽提中均能降低赤桉木材彬纳米粒子的集聚程度,而且还能提高缈纳米粒子的溶出量,其中激光等离子抽提效果最好.

关键词: 赤桉, 彬纳米粒子, 溶出, 超声, 冷冻, 激光等离子

Abstract:

In order to overcome the negative effects, the extractives of the fresh E. camaldulensis shavings, which were obtained by using the sorbitic-, freezing-, laser plasma- and In this paper, micro/nano particles of Eucalyptus camaldulensis (E. camaldulensis) wood were extracted by means of Sorbitic-, freezing-, laser plasma- and ultrasonic-extraction approaches, and the corresponding leaching laws were investigated via slngle-factor tests. The results show that, during the Sorbitic-extraction process, the extraction rate of the micro/nano particles increases with the extraction time, and that some particles in the diameter ranges of 4150 - 5 560, 4150 - 5 560 and 1 110 - 6 440 nm are respectively leached after having been extracted for 1.5, 3.5 and 4. Oh. The volume fractions of these particles, respectively only 0. 3%, 0. 3% and 2. 6%, are enough to give obstructive effects on the permeability and the pulping. Moreover, it is indicated that ultrasonic-, freezing- and laser plasma-extraction approaches can not only reduce the clustering of leached micro/nano par: ticles but also enhance the leaching, especially the laser plasma-extraction approach.

Key words: Eucalyptus camaldulensis, micro/nano particle, leaching, ultrasonic, freezing, laser plasma