华南理工大学学报(自然科学版) ›› 2008, Vol. 36 ›› Issue (3): 37-40.

• 化学化工 • 上一篇    下一篇

加料方式对丙烯酸酯微乳液粒径的影响

吴跃焕 刘述梅 赵建青   

  1. 华南理工大学 材料科学与工程学院, 广东 广州 510640
  • 收稿日期:2007-01-24 修回日期:2007-04-21 出版日期:2008-03-25 发布日期:2008-03-25
  • 通信作者: 赵建青,教授,博士生导师, E-mail:psjqzhao@scut.edu.cn
  • 作者简介:吴跃焕(1968-),女,博士后,副教授,主要从事乳液聚合的研究.E-mail:wuyuehuan123@126.com
  • 基金资助:

    山西省自然科学基金资助项目(2007011035);山西省科技攻关项目(051150);广州市科技攻关项目(2005Z3-D0331)

Influence of Feeding Mode on Particle Size of Acrylate Micro-Latex

Wu Yue-huan  Liu Shu-mei  Zhao Jian-qing    

  1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2007-01-24 Revised:2007-04-21 Online:2008-03-25 Published:2008-03-25
  • Contact: 赵建青,教授,博士生导师, E-mail:psjqzhao@scut.edu.cn
  • About author:吴跃焕(1968-),女,博士后,副教授,主要从事乳液聚合的研究.E-mail:wuyuehuan123@126.com
  • Supported by:

    山西省自然科学基金资助项目(2007011035);山西省科技攻关项目(051150);广州市科技攻关项目(2005Z3-D0331)

摘要: 采用种子乳液聚合法,合成出乳化剂含量为1.5%、聚合物含量为50%、粒径为35.6nm、多分散性指标为0.133的丙烯酸酯微乳液.重点考察了种子乳液制备过程中单体、乳化剂以及引发剂的加料方式对乳胶粒粒径及其分布的影响.研究表明:全滴加法制备种子乳液形成的胶束数目多,成核率高,乳液粒径小;底料中乳化剂、引发剂浓度增大,乳液粒径减小.

关键词: 丙烯酸酯微乳液, 乳胶粒径, 加料方式

Abstract:

Acrylate micro-latex containing 1.5% (mass fraction, below the same) emulsifier and 50% polymer with a particle size of 35.6nm and a polydispersity index of 0. 133 was prepared by means of seed emulsion poly- merization. The particle size and its distribution of the micro-latex affected by the feeding modes of the monomer, the emulsifier and the initiator were then investigated. The results indicate that the dropwise addition may result in a large quantity of micelles, a high nucleation rate and a small particle size, and that the particle size decreases with the content increment of the emulsifier and the initiator pre-added before the polymerization.

Key words: acrylate micro-latex, latex particle size, feeding mode