华南理工大学学报(自然科学版) ›› 2008, Vol. 36 ›› Issue (11): 157-161.

• 材料科学与技术 • 上一篇    

明胶水溶液的静电纺丝成形

赵耀明1  朱锐钿严玉蓉张振斌曾宪岷2   

  1. 1. 华南理工大学 材料科学与工程学院, 广东 广州 510640; 2. 四川大学 高分子科学与工程学院, 四川 成都 610065
  • 收稿日期:2007-12-12 修回日期:2008-07-10 出版日期:2008-11-25 发布日期:2008-11-25
  • 通信作者: 赵耀明(1940-),男,教授,博士生导师,主要从事高分子材料成型加工及功能化研究. E-mail:psymzhao@seut.edu.cn
  • 作者简介:赵耀明(1940-),男,教授,博士生导师,主要从事高分子材料成型加工及功能化研究.
  • 基金资助:

    华南理工大学自然科学基金资助项目(E5040170)

Electrostatic Spinning of Aqueous Gelatin Solution

Zhao Yao-ming1  Zhu Rui-tian1  Yan Yu-rong1  Zhang Zhen-bin1  Zeng Xian-min2   

  1. 1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China; 2. College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, Sichuan, China
  • Received:2007-12-12 Revised:2008-07-10 Online:2008-11-25 Published:2008-11-25
  • Contact: 赵耀明(1940-),男,教授,博士生导师,主要从事高分子材料成型加工及功能化研究. E-mail:psymzhao@seut.edu.cn
  • About author:赵耀明(1940-),男,教授,博士生导师,主要从事高分子材料成型加工及功能化研究.
  • Supported by:

    华南理工大学自然科学基金资助项目(E5040170)

摘要: 以水为溶剂制备明胶溶液进行静电纺丝,在60~65℃纺得明胶超细纤维,探讨了明胶用量、静电电压及纤网收集距离等因素对明胶水溶液静电纺丝成形的影响.结果表明:在60~65℃范围内,明胶溶液的黏度随明胶用量的增加而大幅上升,呈2次指数关系;随明胶用量的降低(从25%降到15%),所得纤维平均直径减小(从266.5nm降为167.7nm);随静电纺丝电压的升高,纤维直径下降,当电压大于17kV后其变化趋于平缓;静电纺丝收集距离在11~21cm之间变化时,所得的纤维直径在165~210nm之间,变化幅度不大.

关键词: 静电纺丝, 明胶, 超细纤维

Abstract:

Uhrafine fibers of gelatin were spun from aqueous gelatin solution via an electrostatic spinning process at 60 - 65 ℃, and the effects of the gelatin dosage, the electrostatic voltage and the spinning distance on the spinning process were investigated. The results indicate that, at 60 - 65 ℃, the viscosity of gelatin/water system greatly increases with the dosage of gelatin in a secondary exponential relationship, that the average diameter of fibers decreases from 266.5nm to 167.7nm corresponding to the gelatin dosage decreasing from 25% to 15% , that the fiber diameter decreases with the increase of spinning voltage to a constant at a voltage of more than 17 kV, and that the diameter slightly changes from 165 to 210 nm when the spinning distance varies form 11 to 21 cm.

Key words: electrostatic spinning, gelatin, uhrafine fiber