华南理工大学学报(自然科学版) ›› 2005, Vol. 33 ›› Issue (11): 31-36.

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共混改性聚四氟乙烯覆铜板的制备

胡福田 文秀芳 皮丕辉 程江 杨卓如   

  1. 华南理工大学 化工与能源学院,广东 广州 510640
  • 收稿日期:2005-02-18 出版日期:2005-11-25 发布日期:2005-11-25
  • 通信作者: 胡福田(1968-),男,博士生,讲师,主要从事精细化工与电子品化学的研究 E-mail:hftian2002@163.com
  • 作者简介:胡福田(1968-),男,博士生,讲师,主要从事精细化工与电子品化学的研究
  • 基金资助:

    东莞市科技局重点项目(东科(2004)1号)

Preparation of Copper Clad Laminaes Based on Polytetraflouroethylene With Blending Modification

Hu Fu-tian  Wen Xiu-fang  Pi Pi-hui  Cheng Jiang  Yang Zhuo-ru,   

  1. College ofChemical and Energy Engineering,South China Univ,ofTech.,Guangzhou 510640,Guangdong,China
  • Received:2005-02-18 Online:2005-11-25 Published:2005-11-25
  • Contact: 胡福田(1968-),男,博士生,讲师,主要从事精细化工与电子品化学的研究 E-mail:hftian2002@163.com
  • About author:胡福田(1968-),男,博士生,讲师,主要从事精细化工与电子品化学的研究
  • Supported by:

    东莞市科技局重点项目(东科(2004)1号)

摘要: 利用聚全氟乙丙烯(FEP)共混改性聚四氟乙烯(P1’FE),制备了高性能聚四氟乙烯覆铜板.采用DSC和SEM分析了上述两种树脂的相容性,研究了偶联剂种类、树脂含量和玻璃纤维布含量等对覆铜板主要性能的影响,并用SEM观察了改性前后覆铜板冲击断面的微观结构.结果表明,聚四氟乙烯与聚全氟乙丙烯相容性能好,共混改性后覆铜板剥离强度从1.8 kN/m提高到2.26 kN/m,抗弯强度从100 MPa提高到134 MPa,而介质损耗因数从8×10-4 降到7×10-4

关键词: 聚四氟乙烯, 覆铜板, 共混, 改性, 剥离强度, 抗弯强度

Abstract:

Copper clad laminates(CCLs)with high performance based on modified polytetrafluoroethylene(PTFE) were prepared by using blended tetrafluoroethylene and hexafluoropopylene(FEP)as the modification resin.The compatibility of the two resins was then analyzed by means of DSC and SEM.Moreover,the efects of coupling agent,resin content and glass cloth content on the main properties of CCLs were investigated.Th e micro-structure of the cross-sections of CCLs based on the PTFE with or without modification were finally explored.Th e results show that there is excellent compatibility between PTFE and FEP,and that,after the modification by blending,the peeling strength of CCLs increases from 1.8 kN/m to 2.26 kN/m,and the flexural strength increases from 100 MPa to 134 MPa.while the dielectric dissipation factor decreases from 8×10-4 to 7×10-4

Key words: polytetrafluoroethylene, copper clad laminate, blending, modification, peeling strength, flexural strength