华南理工大学学报(自然科学版) ›› 2003, Vol. 31 ›› Issue (5): 47-50,55.

• 生物工程 • 上一篇    下一篇

生物陶粒批式硝化过程的特性研究

雒怀庆 胡勇有 陈柱   

  1. 华南理工大学 造纸与环境工程学院‚广东 广州 510640
  • 出版日期:2003-05-20 发布日期:2022-04-27
  • 通信作者: 雒怀庆 (1971-)‚男‚博士生‚主要从事废水生物处理研究.
  • 作者简介:雒怀庆 (1971-)‚男‚博士生‚主要从事废水生物处理研究.

Batch Study on the Nitrification Process Characteristics Using Biological Porcelain Granule#br#

Luo Hua- i qing Hu Yong-you  Chen Zhu   

  1. Research Institute of Chemical Engineering‚South China Univ.of Tech.‚Guangzhou510640‚China
  • Online:2003-05-20 Published:2022-04-27

摘要: 对不同碱度、温度及P/N 质量比下的生物陶粒批式硝化过程进行了研究.结果表明‚一定范围内提高碱度将有利于氨的氧化和促进亚硝酸盐氮的积累‚对二者都适合的氨氮/碳酸氢钠质量比应在1/12~1/16之间.温度对 NO -2 -N 的积累具有十分重要的影响‚当温度低于32℃时‚水中 NO -2 -N 的积累量明显减少‚NO - 3 -N 的生成量大大增加;而当温度为38℃时‚由于亚硝化菌和硝化菌都受到了抑制‚硝化速率下降;当温度为36℃时‚最大 NO -2 -N 生成量可达初始氨氮量的89.94%‚因此对 NO - 2 -N 的积累最为有利.在 P/N 质
量比为0‚1/10和1/5的情况下‚随着P/N 比的增加‚氨的平均氧化速率、NO -2 -N 和 NO - 3 -N 的平均积累速率均下降‚呈负相关关系‚因此为了有效地进行硝化‚应将 P/N 比控制在1/10以下.

关键词: 生物陶粒, 硝化, 生物脱氮

Abstract:  Batch studies on the nitrification process using biological porcelain granule under different alkalinity‚temperature and P/N ratio(in mass) were performed.The results show that increasing the alkalinity in certain range is favorable for ammonium oxidation and NO -2 -N accumulation.Moreover‚the appropriate mass ratio of NH + 4 -N to NaH-CO 3 is1/12~1/16.Temperature has important influence on NO -2 -N accumulation.When temperature is below32℃‚NO -2 -N decreases markedly whereas NO - 3 -accumulates.The nitrosomonas and nitrobacteria will be inhibited and the rate of nitrification will decrease in38℃.The maximal accumulation of NO -2 -N could reach89.94% of theNH +4 -N added at the beginning of the process in36℃‚this suggests that36℃ is the most favorable temperature for the accumulation of NO -2 -N.The nitrification process in three P/N ratios‚i.e.0‚1/10and1/5was studied.It shows that the average oxidation rate of ammonium‚the accumulation rat when P/N ratio increases.This implies that a negative correlativity is between them.Thus‚to make the nitrification process well perform‚P/N ratio should be controlled under1/10.

Key words:  fenton-type catalyst, hydrogen peroxide, catalytic wet oxidation, phenol