华南理工大学学报(自然科学版) ›› 2017, Vol. 45 ›› Issue (8): 35-41.doi: 10.3969/j.issn.1000-565X.2017.08.006

• 汽车工程 • 上一篇    下一篇

基于GDL 非一致孔隙率的 PEMFC 模拟仿真

张智明 沈哲民 商亚鹏 潘涛   

  1. 同济大学 汽车学院//新能源汽车工程中心,上海 201804
  • 收稿日期:2016-04-25 修回日期:2017-02-22 出版日期:2017-08-25 发布日期:2017-07-02
  • 通信作者: 张智明(1979-),男,博士,讲师,主要从事新能源燃料电池发动机及关键零部件技术研究. E-mail:zhangzm@tongji.edu.cn
  • 作者简介:张智明(1979-),男,博士,讲师,主要从事新能源燃料电池发动机及关键零部件技术研究.
  • 基金资助:
    国家自然科学基金资助项目(51405344);47 期教育部留学归国人员科研启动基金项目;同济大学中央高校基本科研业务费专项资金资助项目(1600219247);公路养护装备国家工程实验室开放基金资助项目(310825151129)

Simulation of PEMFC Based on Non-Uniform Porosity of GDL

ZHANG Zhi-ming SHEN Zhe-min SHANG Ya-peng PAN Tao   

  1. School of Automobile Studies∥Clean Energy Automotive Engineering Center,Tongji University,Shanghai 201804,China
  • Received:2016-04-25 Revised:2017-02-22 Online:2017-08-25 Published:2017-07-02
  • Contact: 张智明(1979-),男,博士,讲师,主要从事新能源燃料电池发动机及关键零部件技术研究. E-mail:zhangzm@tongji.edu.cn
  • About author:张智明(1979-),男,博士,讲师,主要从事新能源燃料电池发动机及关键零部件技术研究.
  • Supported by:
    Supported by the National Natural Science Foundtion of China(51405344) and the 47# Scientific Research Foundation for Returned Scholars,Ministry of Education of China

摘要: 目前,针对质子交换膜燃料电池(PEMFC)性能的数值模拟研究大多假设气体扩散层(GDL)的多孔介质孔隙率一致,但实际上 GDL 受双极板脊背压缩产生的变形会导致
孔隙率的非一致性. 文中针对装配压力引起的 GDL 变形及非一致孔隙率情况,基于有限元理论和计算流体力学软件,在 FLUENT 中导入力学分析得到非一致孔隙率的自定义函数(UDF). 模拟结果表明:脊部下方 GDL 由于孔隙率的变化使得沿 Y 方向截面纵向气体的流速往双极板方向的递增;且孔隙率的非一致性导致脊部下方的气体浓度较流道下方降低、水含量增大,产生积水现象,这些变化将不利于燃料电池性能的保持. 然后在验证函数准确性的同时探究了电池温度、湿度等参数随燃料电池电压的变化规律,并研究了燃料电池内部温度的变化. 发现流道下方阴极侧电化学区域比阳极侧温度高,反映了实际燃料电池中阴极侧水堆积现象造成热的传输速度慢于阳极侧的实际情况.

关键词: PEMFC 性能仿真, GDL 变形, 非一致孔隙率, 自定义函数, 电流密度

Abstract: At present,for the numerical simulation of the PEMFC (Proton Exchange Membrane Fuel Cell) perfor- mance,it is assumed that the porous media in the GDL (Gas Diffusion Layer) has a constant porosity.But in fact,the GDL deformation caused by the compression of bipolar plate ribs can lead to the non-uniform porosity of the GDL.In this paper,aiming at the GDL deformation and the non-uniform porosity,which are caused by the assembly pres- sure,based on the finite element theory and the computational fluid dynamics software,a non-uniform porosity func- tion (UDF,User Defined Function) is deduced by introducing the structural mechanics analysis into a FLUENT simu- lation model.Simulation results show that,for the GDL below the rib,the changes of the porosity cause the gas flow rate in the longitudinal section in the Y direction to increase from the middle to the bipolar plates,and that,due to the nonuniformity of the porosity,the gas concentration below the rib is lower than that below the flow chan- nel,and the water content increases leads to a water accumulation phenomenon,which are negative to maintaining the performance of fuel cells.Moreover,the accuracy of the deduced function is verified,meanwhile the change rules of the operating temperature and humidity with the fuel cell voltage are discussed,and the temperature distribution inside the fuel cell is also investigated.It is found that the temperature of the electrochemical region at the cathode side below the flow channel is higher than that at the anode side,which reflects that,for the actual fuel cell,the water accumulation phenomenon at the cathode side causes its heat transfer speed to be slower than that at the anode side.

Key words: PEMFC performance simulation, GDL deformation, non-uniform porosity, user-defined function, current density