华南理工大学学报(自然科学版) ›› 2014, Vol. 42 ›› Issue (1): 11-16.doi: 10.3969/j.issn.1000-565X.2014.01.003

• 机械工程 • 上一篇    下一篇

功能电极钛合金表面TiN 涂层的原位合成

徐安阳 刘志东 李文沛 邱明波 田宗军   

  1. 南京航空航天大学 机电学院,江苏 南京 210016
  • 收稿日期:2013-07-16 修回日期:2013-10-21 出版日期:2014-01-25 发布日期:2013-12-01
  • 通信作者: 徐安阳(1981-),男,博士生,主要从事特种加工研究. E-mail:xuanyang207@nuaa.edu.cn
  • 作者简介:徐安阳(1981-),男,博士生,主要从事特种加工研究.
  • 基金资助:

    国家自然科学基金资助项目(51175256, 51205197);江苏省自然科学基金资助项目(BK2011732);航空基金资助项目(2011ZE52060);江苏省普通高校研究生科研创新计划资助项目(CXLX12_0138)中央高校基本科研业务费专项资金资助

In- Situ Synthesis of TiN Coating on Titanium Alloy Surface by EDM with Functional Electrode

Xu An- yang Liu Zhi- dong Li Wen- pei Qiu Ming- bo Tian Zhong- jun   

  1. College of Mechanical and Electrical Engineering,Nanjing University of Aeronautics and Astronautics,Nanjing 210016,Jiangsu,China
  • Received:2013-07-16 Revised:2013-10-21 Online:2014-01-25 Published:2013-12-01
  • Contact: 徐安阳(1981-),男,博士生,主要从事特种加工研究. E-mail:xuanyang207@nuaa.edu.cn
  • About author:徐安阳(1981-),男,博士生,主要从事特种加工研究.
  • Supported by:

    国家自然科学基金资助项目(51175256, 51205197);江苏省自然科学基金资助项目(BK2011732);航空基金资助项目(2011ZE52060);江苏省普通高校研究生科研创新计划资助项目(CXLX12_0138)中央高校基本科研业务费专项资金资助

摘要: 针对功能电极电火花诱导烧蚀加工钛合金的表面缺陷,通过原加工系统向加工区域通入氮气,利用电火花放电对烧蚀加工表面进行修整,放电产生的热量促使氮气和钛合金表面材料发生化学反应,原位合成了TiN 涂层,并利用扫描电子显微镜、X 射线衍射仪、显微硬度计等检测手段对涂层进行测试.结果表明: 加工过程中电火花放电稳定连续,能量利用率较高; 涂层致密、均匀、连续,主要由TiN 强化相组成,厚度可达400 μm 以上;TiN 涂层显微硬度可达1761.8,是基体硬度的5.7 倍; 涂层与基体之间形成结合强度高的冶金结合且 TiN 相分布比较均匀; 合成反应对电极有很强的反镀作用,电极端面以TiN 强化相为主,能有效地降低电极损耗,同时避免了电极材料对涂层形成的污染,较好地保持涂层中TiN 相的纯度.

关键词: 功能电极, 电火花加工, 原位合成, 钛合金, TiN 涂层

Abstract:

Proposed in this paper is a new method to avoid the defects on titanium alloy surface formed during theEDM- induced ablation machining with functional electrode.In this method,nitrogen gas is injected into the pro-cessing area through the original processing system,and the electric spark discharge is adopted to trim the ma-chined surface. With the help of the heat due to the discharge,a reaction of nitrogen gas and titanium occurs,andthe TiN coating is thus synthesized in situ. It is found from the SEM,XRD and microhardness test results of TiNcoating that (1) the electric spark discharge process is stable and continuous in the process of coating formation andis of efficient energy utilization; (2) the coating is a dense,uniform and continuous layer dominated by TiNstrengthening phase,with a thickness of more than 400μm; (3) the microhardness of the coating reaches 1761.8,which is 4.7 times more than that of the matrix; (4) there exists a metallurgical combination with high bondingstrength and even TiN phase distribution between the coating and the matrix; and (5) the synthesis reaction has astrong reverse plating effect on the electrode,which causes a TiN strengthening phase- dominated electrode endface,effectively reduces the electrode spoilage,avoids the coating pollution caused by electrode elements,and effe-ctively maintains the purity of TiN phase in the coating.

Key words: function electrode, electrical discharge machining, in- situ synthesis, titanium alloy, TiN coating

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