华南理工大学学报(自然科学版) ›› 2013, Vol. 41 ›› Issue (12): 43-48.doi: 10.3969/j.issn.1000-565X.2013.12.008

• 环境科学与技术 • 上一篇    下一篇

铁改性膨润土光催化-Fenton 降解造纸法烟草薄片废水

莫立焕 周志明 王玉峰 鲁礼成   

  1. 华南理工大学 制浆造纸工程国家重点实验室∥植物资源化学与化工联合实验室,广东 广州 510640
  • 收稿日期:2013-01-25 修回日期:2013-05-24 出版日期:2013-12-25 发布日期:2013-11-19
  • 通信作者: 莫立焕(1970-),男,博士,高级工程师,主要从事制浆清洁生产与污染控制研究. E-mail:lhmo@scut.edu.cn
  • 作者简介:莫立焕(1970-),男,博士,高级工程师,主要从事制浆清洁生产与污染控制研究.
  • 基金资助:

    国家 “973” 计划项目(2010CB732205)

Photocatalysis- Fenton Degradation of Papermaking- Reconstituted Tobacco Slice Wastewater Using Fe- Bent

Mo Li- huan Zhou Zhi- ming Wang Yu- feng Lu Li- cheng   

  1. State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China∥United Laboratory of Plant Resources Chemistry and Chemical Engineering,Guangzhou 510640,Guangdong,China
  • Received:2013-01-25 Revised:2013-05-24 Online:2013-12-25 Published:2013-11-19
  • Contact: 莫立焕(1970-),男,博士,高级工程师,主要从事制浆清洁生产与污染控制研究. E-mail:lhmo@scut.edu.cn
  • About author:莫立焕(1970-),男,博士,高级工程师,主要从事制浆清洁生产与污染控制研究.
  • Supported by:

    国家 “973” 计划项目(2010CB732205)

摘要: 以铁离子交换改性钠基膨润土, 制得一种非均相 Fenton 催化剂, 利用扫描电镜和X 射线衍射仪对催化剂进行了表征, 并将其用于光催化深度处理造纸法烟草薄片废水. 采用响应面分析法通过建立出水 CODCr 与各因素之间的 Box- Behnken 数学模型, 对光催化处理工艺进行优化. 结果表明:在最佳实验条件(pH 值 2.7、 H2O2 用量 0. 2%、 催化剂用量1750mg/L)下, 处理后废水 CODCr 低至 60.44mg/L;铁改性膨润土在反应过程中具有较低的铁溶出量和良好的重复使用性.

关键词: 废水处理, 烟草薄片废水, 铁改性膨润土, 非均相 Fenton, 响应面分析

Abstract:

A heterogeneous Fenton catalyst,namely Fe- Bent,was prepared from Na- Bent through cation exchangeand was characterized by means of scan electron microscopy and X- ray diffraction.Then,the catalyst was used forthe advanced treatment of papermaking- reconstituted tobacco slice wastewater,and a Box- Behnken mathematicalmodel describing the relationship between wastewater CODCr and affecting factors was then established via the re-sponse surface analysis,with the photo- catalytic treatment process being finally optimized.The results show that(1) under optimal conditions,that is,an initial pH value of 2.7,a H2O2 dosage of 0.2% and a catalyst dosage of1750mg/L,the CODCr is as low as 60.44mg/L; (2) only a small amount of Fe ions leach from Fe- Bent during thereaction; and (3) the prepared catalyst can be easily recovered and reused.

Key words: wastewater treatment, tobacco slice wastewater, Fe- Bent, heterogeneous Fenton, response surfaceanalysis