华南理工大学学报(自然科学版) ›› 2011, Vol. 39 ›› Issue (3): 83-89.doi: 10.3969/j.issn.1000-565X.2011.03.017

• 动力与电气工程 • 上一篇    下一篇

焦炉煤气合成甲醇和发电系统的设计及性能分析

张学镭 陈海平 王松岭 周兰欣   

  1. 华北电力大学 电站设备状态监测与控制教育部重点实验室,河北 保定 071003
  • 收稿日期:2010-03-24 修回日期:2010-06-02 出版日期:2011-03-25 发布日期:2011-02-01
  • 通信作者: 张学镭(1977-),男,博士,讲师,主要从事先进能源动力系统的建模与优化等研究 E-mail:xueleizh@163.com
  • 作者简介:张学镭(1977-),男,博士,讲师,主要从事先进能源动力系统的建模与优化等研究
  • 基金资助:

    中央高校基本科研业务费专项资金资助项目(09MG34)

Design and Performance Analysis of Poly-Generation System for Methanol Synthesis and Electric Power Generation with Coke Oven Gas as Raw Material

 Zhang Xue-lei  Chen Hai-ping  Wang Song-ling  Zhou Lan-xin   

  1. University of north China electric power equipment state monitoring and control power the key laboratory, heibei baoding 071003
     
  • Received:2010-03-24 Revised:2010-06-02 Online:2011-03-25 Published:2011-02-01
  • Contact: 张学镭(1977-),男,博士,讲师,主要从事先进能源动力系统的建模与优化等研究 E-mail:xueleizh@163.com
  • About author:张学镭(1977-),男,博士,讲师,主要从事先进能源动力系统的建模与优化等研究
  • Supported by:

    中央高校基本科研业务费专项资金资助项目(09MG34)

摘要: 为合理利用焦炉煤气,设计了以焦炉煤气为原料的鲁奇气相法甲醇合成系统的工艺流程,基于Aspen Plus软件模拟得到了系统的关键参数;对燃用焦炉煤气的燃气-蒸汽联合循环的性能进行了计算,并与燃用天然气时的性能进行了比较;设计了利用焦炉煤气合成甲醇和发电的并联式多联产系统,并与单产系统的性能进行了比较.结果表明:采用炉前补碳工艺可提高甲醇合成产量,并降低能耗6%左右;由天然气改烧焦炉煤气后,联合循环的净功率下降了0.87%,热效率下降了0.91%;甲醇–发电并联式多联产系统的热效率比单产系统高约两个百分点,采用炉前补碳工艺的多联产系统热经济性最优.

关键词: 焦炉煤气, 甲醇, 燃气-蒸汽联合循环, 多联产, 性能

Abstract:

In order to reasonably utilize coke oven gas(COG),first,a Lurgi gas-phase methanol synthesis system was designed,with COG as the raw material,and the key parameters of the system were obtained by the simulation with Aspen Plus.Next,the performance of gas-steam combined cycle firing COG was calculated and compared with that firing natural gas.Then,a parallel poly-generation system for gas-phase methanol synthesis and electric power generation was designed.Finally,a performance comparison was performed between the designed system and the exi-sting one-product system.The results show that the carbon supplementation before reformer increases the methanol yield and decreases the energy consumption by about 6%,that the net power and thermal efficiency of the combined cycle respectively decrease by 0.87% and 0.91% when substituting COG for natural gas,and that the thermal efficiency of the poly-generation system is about two points of percentage higher than that of the one-product system.Thus,it comes to the conclusion that the proposed poly-generation system with carbon supplementation before reformer is of the highest thermo-economic benefit.

Key words: coke oven gas, methanol, gas turbine combined cycle, poly-generation, performance