The activated effects of two kinds of alkali-activators , namely , sodium hydroxide solution and sodium silicate solution , on metakaolinite were investigated using the large solid-liquid ratio method. In the investigation , the slurry was separated after a period of activation , and the separated solutions and powders were then analyzed , respectively. It is found that (1) in the separated solution after the reaction between sodium silicate solution and metakaolin , the polymerization degree of Si increases with the reaction time , the soluble Al polymerizes with the siliceous ion , and the separated powder contains both the fragment of metakaolinite and the gel of silicate-aluminium;( 2) in the separated solution after the reaction between sodium hydroxide solution and metakaolin , the contents of Si and Al increase with the reaction time , the soluble Al does not polymerize with the siliceous ion , and the separated powder only contains the fragment of metakaolinite; and (3) the siliceous ion in sodium silicate solution plays a significant role in the geopolymeric reaction.