Journal of South China University of Technology(Natural Science) >

2010 , Vol. 38 >Issue 8: 7 - 11

DOI: https://doi.org/10.3969/j.issn.1000-565X.2010.08.002

Chemistry & Chemical Engineering

Photochemical and Electrochemical Behaviors of Ferroceneylazobenzoic Acid Solution

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  • Research Institute of Materials Science, South China University of Technology, Guangzhou 510640, Guangdong, China
任碧野（1965-），男，教授，博士生导师，主要从事功能高分子材料研究．

Received date: 2009-07-14

  Revised date: 2009-10-08

  Online published: 2010-08-25

Supported by

国家自然科学基金资助项目（50873037）

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Abstract

A novel amphiphilic ferroceneylazobenzoic acid （FcAzCOOH） with optical and redox activities was synthesized, and the product was identified and characterized by means of elemental analysis, 1H NMR and FT-IR. Then, the photochemical behavior of FcAzCOOH in tetrahydrofuran solution was invenstigated by means of UV-Vis, with an excellent photoisomerization behavior being discovered. Moreover, the electrochemical behavior of FcAz- COOH in polar DMF solution was analyzed by means of cyclic voltarnmetry. The results show that the electrochemical response of FcAzCOOH is dispersion-controlled and reversible, and that UV light has no obvious effect on the electrochemical behavior of FcAzCOOH.

Key words： azobenzene; ferrocene; photochemistry; electrochemistry

Cite this article

Ren Bi-ye Zhang Yi Li Chong-qing Liu Xin-xing Tong Zhen . Photochemical and Electrochemical Behaviors of Ferroceneylazobenzoic Acid Solution[J]. Journal of South China University of Technology(Natural Science), 2010 , 38(8) : 7 -11 . DOI: 10.3969/j.issn.1000-565X.2010.08.002

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