By using Hibiscus cannabines as the raw material,this paper analyzes the chemical component of the material,investigates the optimal kraft pulping（KP） conditions at different H factor,and discusses the element chlorine-free（ECF） bleaching of the KP pulp and corresponding bleaching process.It is found that Hibiscus cannabines is a good material for paper making,with the chemical composition as follows： 45.0% of nitrate-ethanol cellulose,16.5% of Klason lignin,pentosan and low content of extraction.Moreover,the results indicate that,in the optimal pulping conditions,namely,a H-factor of 1 000,an active alkali dosage of 20% and a sulphidity of 22%,screened pulp with a yield of 44.9%,a Kappa number of 20.4 and a residual alkali content of 11.67 g/L can be obtained,and that ECF bleaching sequence（ODED） can produce pulp with a brightness of 82.3%ISO when OD0,2%-EpD1,1.5% process is employed.