Journal of South China University of Technology(Natural Science) >
Influence of HPMA on Properties of Acrylate Latex and Corresponding Re-Rispersible Powder
Received date: 2009-08-11
Revised date: 2009-10-12
Online published: 2010-08-25
Supported by
国家自然科学基金资助项目(50803017)
Acrylate polymer latices with soft core and hard shell were synthesized via the emulsion polymerization of β-hydroxy propylmethacrylate (HPMA) and methacrylic acid ( MAA), and the corresponding re-dispersible powder was also prepared. Moreover, the influence of HPMA dosage on the film-forming ability, the re-dispersibility and the water resistance of the original latex and its re-dispersible powder were discussed. Experimental results show that, at a HPMA dosage of 1.2% (mass fraction, the same below) , the film-forming ability and the water resist- ance behavior of the original latex and its re-dispersible powder are optimal and the re-dispersibility is well maintained. The absorbance analysis indicates that, when the HPMA dosage is not more than 1.2%, the powder possesses excellent re-dispersibility, high dispersity ( up to 90% ) and small mean absorbance variation ( less than 10% ). DSC results show that the film of the original latex is of two glass transition temperatures; one is 6. 98℃ and the other is 30. 11 ℃, which means that the polymer particles have a two-phase core-shell configuration. This configuration is also verified by TEM photographs. Moreover, SEM results demonstrate that both the original latex and the re-dispersible powder are of excellent film-forming ability, and that micro-phase separation occurs during the film-forming of the original latex, which further testifies the core-shell configuration of the latex.
Zhang Xin-ya He Yan-ping Jiang Yu-ling Pei Yong-bing Chen Huan-qin . Influence of HPMA on Properties of Acrylate Latex and Corresponding Re-Rispersible Powder[J]. Journal of South China University of Technology(Natural Science), 2010 , 38(8) : 23 -28 . DOI: 10.3969/j.issn.1000-565X.2010.08.005
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