Chemistry & Chemical Engineering

Chlorine Dioxide Bleaching Reinforced by Alkaline Extraction and Corresponding ECF Bleaching Sequences for Wheat Straw Pulp

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  • 1. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China; 2. School of Chemistry Engineering and Material, Dalian Polytechnic University, Dalian 116034, Liaoning, China
赵德清(1975-),男,博士生,主要从事制浆清洁生产与污染控制研究.

Received date: 2009-08-11

  Revised date: 2009-10-26

  Online published: 2010-08-25

Supported by

国家科技支撑计划项目(2006BA032806-2)

Abstract

Four kinds of alkaline extraction approaches, including the conventional, the oxygen-reinforced, the H2O2-reinforced and the oxygen-and-H2O2-reinforced ones (E, E0, Ep and E0p) , were used to modify ClO2-delignified (D0) wheat straw pulp, and the modification effects of these four approaches on the subsequent bleaching stage (D1) were explored. In addition, various elemental chlorine-free (ECF) bleaching sequences, such as D0ED1, D0P, DoA/QP, D0EP, D0EpD1 and D0EpP, were comparatively investigated. The results indicate that ( 1 ) the modification effects of different alkaline extraction approaches on the residual lignin of Do stage are different from one other; (2) for the subsequent D1 stage, the bleachability of D1 pulp varies in an order of D0E0P 〉 D0Ep 〉 D0E0 〉 D0E; (3) in the D0ED1 bleaching sequences, the increase of ClO2 dosage in D1 stage results in the brightness enhancement in a certain degree, especially at an optimized ClO2 dosage of 0. 8% -1.0% ; (4) as compared with the other sequences, D0EpD1 and D0EpP sequences are both of better bleaching effect; and (5) with D0EpD1 and DoEpP bleaching sequences, the final brightness of bleached wheat straw pulp reaches 82.3% ISO and 83.8% ISO, respectively, which means that both D0EpD1 and DoEpP sequences are applicable to the ECF short-sequence bleaching of wheat straw pulp.

Cite this article

Zhao De-qing Chen Ke-fu Mo Li-huan Li Jun Xu Jun Yang Ren-dang Yang Fei . Chlorine Dioxide Bleaching Reinforced by Alkaline Extraction and Corresponding ECF Bleaching Sequences for Wheat Straw Pulp[J]. Journal of South China University of Technology(Natural Science), 2010 , 38(8) : 45 -50 . DOI: 10.3969/j.issn.1000-565X.2010.08.009

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