Materials Science & Technology

Investigation into Reinforcement of NR/SBR/BR Blends with Wood Cellulose Nanocrystals

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  • School of Materials Science and Engineering,South China university of Technology,Guangzhou 510640,Guangdong,China
古菊( 1961-) ,女,博士,副教授,主要从事聚合物复合材料的制备、结构与性能研究.

Received date: 2016-04-22

  Revised date: 2016-06-19

  Online published: 2016-12-31

Supported by

Supported by the National Natural Science Foundation of China( 51173046)

Abstract

Clubbed wood cellulose nanocrystals ( WNC) were prepared via the acid hydrolysis of wood powders and were co-coagulated with natural rubber ( NR) latex to form a NR/WNC mixture.Then,the mixture was blended with butadiene-styrene rubber ( SBR) ,butadiene rubber ( BR) and carbon black ( CB) to obtain WNC /CB /NR/ SBR/BR composites,and the influence of the partial replacement of CB with WNC on the properties of NR/SBR/ BR blends was investigated.The results show that ( 1) as compared with the blends reinforced by 45 phr CB,the Payne effect of the composites with WNC weakens apparently,the processability improves obviously,the mechanical properties maintain well,the heat build-up decreases by 18. 4%,and the permanent set due to compression fatigue is generally lower than 5%; ( 2) the resistance to flex cracking of the composites filled with 5 ~ 10 phr WNC keeps constant,and the abrasion resistance of the composites filled with 5 phr WNC keeps consistent; ( 3) with the increase of WNC dosage,the loss tangent ( tan δ) value of the composites at 0℃ first increases and then decreases,while the one at 60 ℃ gradually decreases; ( 4) the temperature corresponding to 5% mass loss decreases,while that corresponding to the maximum mass loss rate changes slightly; and ( 5) the addition of WNC helps to maintain the aging performance of the composites.Moreover,SEM results demonstrate that the added WNC with a small quantity displays good homogeneity and strong interfacial interaction with the rubber matrix.

Cite this article

GU Ju HUANG Shi-wen WAN Peng XIAO Hai-yan . Investigation into Reinforcement of NR/SBR/BR Blends with Wood Cellulose Nanocrystals[J]. Journal of South China University of Technology(Natural Science), 2017 , 45(2) : 122 -129 . DOI: 10.3969/j.issn.1000-565X.2017.02.017

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