Journal of South China University of Technology(Natural Science) >
Properties of TEMPO- Oxidized Wood Fiber and Its Effects on Paper Properties
Received date: 2013-05-16
Revised date: 2013-06-19
Online published: 2013-09-03
Supported by
国家 “973” 计划项目(2010CB732206);教育部新世纪人才支持计划项目(D08001Ⅲ)
In the investigation,the wood fibers from butterfly eucalyptus were oxidized in the 2,2,6,6- tetrameth-ylpiperidine-1- oxyradical (TEMPO) / NaBr/ NaClO oxidization system,and the morphologies and properties of the wood fibers before and after oxidation were characterized by using a fiber quality analyzer (FS300),a dynamic drainage jar (DDJ) and an optical microscope.Then,the oxidized fibers were used to prepare the transparent pa-per,and the effects of the NaClO dosage on the paper properties were discussed.The results show that (1) the in-crease of the NaClO dosage with constant TEMPO and NaBr dosages causes an average fiber length decrease of 0.38mm,an average fiber width increase of 4.7μm,a fine fiber content increase of 8 times and a fiber curl value decrease of 13.9 percentage points as well as a poor pulp drainage property; and (2) as compared with the transparent paper from the wood fibers without the TEMPO treatment,that with the TEMPO treatment achieves a higher tensile strength and a greater elastic modulus with a 5 times tensile index,a 7 times elastic modulus and a 27.0% surface roughness as well as a transparency of 87%.
Chen Gang Chen Qing- xia . Properties of TEMPO- Oxidized Wood Fiber and Its Effects on Paper Properties[J]. Journal of South China University of Technology(Natural Science), 2013 , 41(10) : 7 -12,19 . DOI: 10.3969/j.issn.1000-565X.2013.10.002
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