Journal of South China University of Technology (Natural Science Edition) ›› 2009, Vol. 37 ›› Issue (12): 70-74,80.

• Chemistry & Chemical Engineering • Previous Articles     Next Articles

Fractal Analysis of Pore Structure of Eucalyptus Pulp Fibers

Guo Wen-fie  Wan Jin-quan  Ma Yong-wen  Wang Yan   

  1. School of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2009-03-26 Revised:2009-05-02 Online:2009-12-25 Published:2009-12-25
  • Contact: 郭文杰(1968-),男,博士后,主要从事制浆造纸污染控制的研究. E-mail:kwauk001@163.com
  • About author:郭文杰(1968-),男,博士后,主要从事制浆造纸污染控制的研究.
  • Supported by:

    国家“863”计划项目(2007AA032433);广东省重点科技攻关项目(2008A0302008);广东省科技计划项目(20088030302035);广东省节能减排重大专项项目(2008A080800003)

Abstract:

The pore structure of eucalyptus pulp fibers was investigated by means of atomic force microscopy (AFM) and low-temperature nitrogen adsorption. Then, based on the fractal theory, the pore structure was further analyzed. AFM observation indicates that the eucalyptus pulp fibers are of a pore structure with self-similarity, which can be analyzed based on the fractal theory. Low-temperature nitrogen adsorption measurement shows that the fibers are of pore surface, and that the pores are mainly in a mesopore range, with an average size of 4. 9 nm, a BET specific surface area of 4. 83 m2/g and a total pore volume of 0. 005 8 cm3/g. Moreover, fractal analysis and calculation indicate that the pore structure of the fibers is of obvious fractal property in a dimension of 2.82, which means that the fibers are of rough and pore surface. It is also found that the fractal dimension of eucalyptus pulp fibers closely relates to the macroscopic properties such as water retention value.

Key words: eucalyptus pulp fiber, fractal, fractal dimension, pore structure