Journal of South China University of Technology(Natural Science Edition) ›› 2004, Vol. 32 ›› Issue (12): 25-29.doi: 1000-565X(2004)12-0025-05

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Oxidation of Diesel Particulate Matters by Using Copper-contained Catalysts

Deng Yao-jie1 Fu Ming-li2 Ye Da-i qi2 Liang Hong3   

  1. 1.Institute of Environmental Protection Science of Zhongshan City‚Zhongshan 528403‚Guangdong‚China; 2.College of Environmental Science and Engineering‚South China Univ.of Tech.‚Guangzhou 510640‚Guangdong‚China; 3.Dept.of Light Chemical Engineering‚Guangzhou Univ.‚Guangzhou 510091‚Guangdong‚China
  • Received:2004-06-09 Online:2004-12-20 Published:2015-09-08
  • Contact: 叶代启 E-mail:cedqye@scut.edu.cn
  • About author:邓耀杰(1968-)‚男‚工程师‚主要从事环境科学、环境影响评价和环境保护规划研究。E-mail:dyja20040112@sohu.com

Abstract: Catalysts Cu-K-V-[-Me(Me=Pt‚MnO2‚NiO‚or SnO2)]/TiO2/γ-Al2O3/cordierite were prepared and then mixed with the particulate matters (PMs) from a min-i type diesel engine.Thus‚the activities of the catalysts were tested by DSC and TG analyses.It is indicated by DSC analysis that the ignition temperature of soluble organic fraction (SOF) can be reduced to432.62K when Cu-K-V-SnO2is used‚which is much lower than the corresponding 523.27K when no catalyst is used.Cu-K-V-NiO can help reduce the temperature to687.97K for the combustion of graphitic solid fraction (GSF).Furthermore‚the temperature for the complete combustion of PMs reaches only766.88 K with the presence of Cu-K-V-NiO.It is also indicated by TG analysis that the presence of Cu-K-V-NiO leads to an abatement efficiency of90.83% at700.65K‚accompanied by91.6% at710.05K for Cu-K-V-Pt‚and81.7% at 725.65K for Cu-K-V-SnO2‚respectively.The maximum reduction of soot reaches38% when Cu-K-V-SnOis used in real exhaust‚which is little higher than the value of25%~35% for commercial products.

Key words: diesel, particulate matter, catalytic oxidation, copper-contained catalyst

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