收稿日期: 2024-03-11
网络出版日期: 2024-08-22
基金资助
内蒙古自然科学基金青年项目(2022QN05023);广东省基础与应用基础研究基金项目(2021A1515110525);宁波市自然科学基金项目(2022J318)
Microstructure and Mechanical Properties of SiC Particle Reinforced AlMgScZr Composites by Selective Laser Melting
Received date: 2024-03-11
Online published: 2024-08-22
Supported by
the Inner Mongolia Natural Science Foundation Youth Project(2022QN05023);the Guangdong Basic and Applied Basic Research Foundation(2021A1515110525)
铝基复合材料具有硬度高、切削加工难度大的特点。为了实现高比强度、高比模量铝基复合材料的近净成形,该文利用激光增材制造技术制备了10%(体积分数)微米级SiC颗粒增强AlMgScZr复合材料,建立了激光能量密度、扫描速率与复合材料成形质量的对应关系,通过光学显微镜(OM)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)和万能试验机对微观组织和力学性能进行表征和测试,探讨了微米级SiC颗粒对选区激光熔化(SLM)成形铝基复合材料凝固组织和力学性能的作用机理。结果表明:在铺粉层厚为30 μm、扫描间距为0.12 mm、激光功率为260 W、扫描速率为1 000 mm/s的工艺参数下,可获得成形质量最佳的SiC/AlMgScZr复合材料,其致密度可达99.81%;激光熔覆过程中,SiC颗粒与Al基体之间发生了剧烈的界面反应,SiC颗粒尖角明显钝化,原位生成的微米级针状Al4SiC4条带与残余SiC颗粒形成混合增强结构;时效态SiC/AlMgScZr复合材料的抗拉强度为379 MPa、延伸率为12%、弹性模量为84 GPa,其断裂形式为Al基体的韧性断裂和Al4SiC4相的脆性解理断裂,大量交错分布的针状Al4SiC4条带是材料发生过早失效断裂的主控因素。
马国楠 , 张乐 , 欧阳 , 史利军 , 鲁仁义 , 程英晔 , 陈越 . 选区激光熔化SiC颗粒增强AlMgScZr复合材料的微观组织与力学性能[J]. 华南理工大学学报(自然科学版), 2025 , 53(1) : 118 -128 . DOI: 10.12141/j.issn.1000-565X.240108
Aluminum matrix composites have the characteristics of high hardness and difficult machining. In order to achieve near-net forming of aluminum matrix composites with high specific strength and high specific modulus, micron SiC particles with volume fraction of 10% reinforced AlMgScZr composites were fabricated using selective laser melting (SLM) technique. The relationship between the laser energy density and scanning rate and the forming quality of the composite was established. The microstructure and mechanical properties were characterized and tested by optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and universal testing machine. The effect of micron SiC particles on the solidification structure and mechanical properties of SLMed aluminum matrix composites was investigated. The results show that the best quality composite could be obtained under the conditions of layer thickness of 30 μm, scanning spacing of 0.12 mm, laser power of 260 W, scanning rate of 1 000 mm/s, and its relative density was up to 99.81%. During the laser cladding process, there was a strong interfacial reaction between SiC particles and Al matrix. Micron-sized acicular Al4SiC4 bands were formed in situ, and the sharp corners of SiC particles are obviously passivated. Al4SiC4 bands and the residual SiC particles formed a mixed reinforced structure. The optimal tensile strength, elongation and elastic modulus of aged SiC/AlMgScZr composites were 379 MPa, 12% and 84 GPa, respectively. The fracture behavior of the composites included ductile fracture of Al matrix and brittle cleavage fracture of Al4SiC4 phases. A large number of cross-distributed acicular Al4SiC4 bands were the main factors leading to premature failure and fracture of SiC/AlMgScZr composites.
| 1 | DEBROY T, WEI H L, ZUBACK J,et al .Additive manufacturing of metallic components-process,structure and properties[J].Progress in Materials Science,2018,92:112-224. |
| 2 | ZHANG J L, GAO J B, SONG B,et al .A novel crack-free Ti-modified Al-Cu-Mg alloy designed for selective laser melting[J].Additive Manufacturing,2020,38:101829/1-12. |
| 3 | WEIDMANN J, GRO?MANN A, MITTELSTEDT C .Laser powder bed fusion manufacturing of aluminum honeycomb structures:theory and testing[J].International Journal of Mechanical Sciences,2020,180:105639/1-18. |
| 4 | OLAKANMI E O, COCHRANE R F, DALGARNO K W .A review on selective laser sintering/melting (SLS/SLM) of aluminium alloy powders:processing,microstructure,and properties[J].Progress in Materials Science,2015,74:401-477. |
| 5 | 王悦,王继杰,张昊,等 .热处理对激光选区熔化AlSi10Mg合金显微组织及力学性能的影响[J].金属学报,2021,57(5):613-622. |
| WANG Yue, WANG Jijie, ZHANG Hao,et al .Effects of heat treatments on microstructure and mechanical properties of AlSi10Mg alloy produced by selective laser melting[J].Acta Metallurgica Sinica,2021,57(5):613-622. | |
| 6 | GU D D, YANG Y, XI L X,et al .Laser absorption behavior of randomly packed powder-bed during selective laser melting of SiC and TiB2 reinforced Al matrix composites[J].Optics and Laser Technology,2019,119:105600/1-9. |
| 7 | LI X P, JI G, CHEN Z,et al .Selective laser melting of nano-TiB2 decorated AlSi10Mg alloy with high fracture strength and ductility[J].Acta Materialia,2017,29:183-193. |
| 8 | XI L, GU D D, GUO S,et al .Grain refinement in laser manufactured Al-based composites with TiB2 ceramic[J].Journal of Materials Research and Technology,2020,9(3):2611-2622. |
| 9 | GAO C, XIAO Z, LIU Z,et al .Selective laser melting of nano-TiN modified AlSi10Mg composite powder with low laser reflectivity[J].Materials Letters,2019,236:362-365. |
| 10 | DAI D H, GU D D .Influence of thermodynamics within molten pool on migration and distribution state of reinforcement during selective laser melting of AlN/AlSi10Mg composites[J].International Journal of Machine Tools and Manufacture,2016,100:14-24. |
| 11 | XI L X, ZHANG H, WANG P,et al .Comparative investigation of microstructure,mechanical properties and strengthening mechanisms of Al-12Si/TiB2 fabricated by selective laser melting and hot pressing[J].Ceramics International,2018,44(15):17635-17642. |
| 12 | XI L X, DING K, ZHANG H,et al .In-situ synthesis of aluminum matrix nanocomposites by selective laser melting of carbon nanotubes modified Al-Mg-Sc-Zr alloys[J].Journal of Alloys and Compounds,2022,891:162047/1-9. |
| 13 | WANG J H, LIU T, LUO L S,et al .Selective laser melting of high-strength TiB2/AlMgScZr composites:microstructure,tensile deformation behavior,and mechanical properties[J].Journal of Materials Research and Technology,2022,16:786-800. |
| 14 | ZHAO X, GU D D, MA C L,et al .Microstructure characteristics and its formation mechanism of selective laser melting SiC reinforced Al-based composites[J].Vacuum,2019,160:189-196. |
| 15 | 马国楠,樊子煜,杨鹏伟,等 .选区激光熔化TiC/AlMgScZr复合材料的成形工艺研究[J].兵器材料科学与工程,2023,46(3):41-47. |
| MA Guonan, FAN Ziyu, YANG Pengwei,et al .Forming process of TiC/AlMgScZr composites by selective laser melting[J].Ordnance Material Science and Engineering,2023,46(3):41-47. | |
| 16 | MA R L, PENG C Q, CAI Z Y,et al .Manipulating the microstructure and tensile properties of selective laser melted Al-Mg-Sc-Zr alloy through heat treatment[J].Journal of Alloys and Compounds,2020,831:154773/1-10. |
| 17 | ZHAO J H, XUE X, WANG B B,et al .Selective laser melting Al-3.4Mg-0.5Mn-0.8Sc-0.4Zr alloys:from melting pool to the microstructure and mechanical pro-perties[J].Materials Science and Engineering:A,2021,825:141889/1-10. |
| 18 | BAYOUMY D, SCHLIEPHAKE D, DIETRICH S,et al .Intensive processing optimization for achieving strong and ductile Al-Mn-Mg-Sc-Zr alloy produced by selective laser melting[J].Materials & Design,2021,198:109317/1-15. |
| 19 | ARUNACHALAM R, KRISHNAN P K, MURALIRAJA R .A review on the production of metal matrix composites through stir casting-furnace design,properties,challenges,and research opportunities[J].Journal of Manufacturing Processes,2019,42:213-245. |
| 20 | TJONG S C, MA Z Y .Microstructural and mechanical characteristics of in situ metal matrix composites[J].Materials Science & Engineering R-Reports,2000,29(3/4):49-113. |
| 21 | VIALA J C, FORTIER P, BOUIX J .Stable and metastable phase equilibria in the chemical interaction between aluminium and silicon carbide[J].Journal of Materials Science,1990,25:1842-1850. |
| 22 | GU D D, CHANG F, DAI D H .Selective laser melting additive manufacturing of novel aluminum based composites with multiple reinforcing phases[J].Journal of Manufacturing Science and Engineering,2015,137:021010-1-021010-11. |
| 23 | ZHOU S Y, SU Y, WANG H,et al .Selective laser melting additive manufacturing of 7xxx series Al-Zn-Mg-Cu alloy:cracking elimination by co-incorporation of Si and TiB2 [J].Additive Manufacturing,2020,36:101458/1-12. |
| 24 | TAN Q Y, FAN Z Q, TANG X Q,et al .A novel strategy to additively manufacture 7075 aluminium alloy with selective laser melting[J].Materials Science and Engineering:A,2021,821:141638/1-15. |
| 25 | ANANDKUMAR R, ALMEIDA A, COLA?O R,et al .Microstructure and wear studies of laser clad Al-Si/SiC(p) composite coatings[J].Surface and Coatings Technology,2007,201(24):9497-9505. |
| 26 | SPIERINGS A B, DAWSON K, KERN K,et al .SLM-processed Sc- and Zr-modified Al-Mg alloy:mechanical properties and microstructural effects of heat treatment[J].Materials Science and Engineering A,2017,701:264-273. |
/
| 〈 |
|
〉 |