材料科学与技术

Q235钢在广东省输电杆塔现场的大气腐蚀行为

  • 高岩 黄殷辉 郑志军 孟晓波 廖永力 李锐海
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  • 1. 华南理工大学 材料科学与工程学院,广东 广州,510640; 2. 华南理工大学 机械与汽车工程学院,广东 广州,510640; 3. 南方电网科学研究院有限责任公司,广东 广州,510080
高岩( 1962-) ,女,博士,教授,主要从事大气腐蚀、纳米材料制备与表征等研究

收稿日期: 2017-09-28

  修回日期: 2017-10-18

  网络出版日期: 2018-06-01

基金资助

国家自然科学基金资助项目( 51471072)

Atmospheric Corrosion Behavior of Q235 Steel Exposed on Transmission Tower Sites of Guangdong Province

  • GAO Yan HUANG Yinhui ZHENG Zhijun MENG Xiaobo LIAO Yongli LI Ruihai
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  •  1. School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China; 2. School of Mechanical and Automotive Engineering,South China University of Technology,Guangzhou 510640,Guangdong, China; 3. Electric Power Research Institute,CSG,Guangzhou 510080,Guangdong,China
高岩( 1962-) ,女,博士,教授,主要从事大气腐蚀、纳米材料制备与表征等研究

Received date: 2017-09-28

  Revised date: 2017-10-18

  Online published: 2018-06-01

Supported by

 Supported by the National Natural Science Foundation of China( 51471072) 

摘要

基于广东省输电线路分布情况,在城市、工业、海洋和乡村 4 种环境中选取有代 表性的 10 条杆塔线路,通过 1 年的现场暴露实验研究了杆塔用 Q235 钢的大气腐蚀行为, 在 6、12 个月时各取样一次; 利用失重法测量各挂片的单位面积腐蚀失重,研究了不同环 境中的腐蚀失重规律,并采用 X 射线衍射仪( XRD) 和扫描电子显微镜( SEM) 对腐蚀产物 结构和微观形貌进行表征. 结果表明: 广东省大气腐蚀等级主要为 C3,其次为 C2,属于中 度腐蚀; 不同特征的环境对大气腐蚀的影响从重到轻依次为重工业、海洋 + 轻工业复合、 海洋和特大城市、中小型城市及乡村; 在 12 个月的试验周期内,Q235 钢前 6 个月的腐蚀 速率明显高于后 6 个月; 腐蚀产物主要为花瓣网状和细针状结构的 α-FeOOH 和 γFeOOH,在海洋环境中还出现少量 β-FeOOH

本文引用格式

高岩 黄殷辉 郑志军 孟晓波 廖永力 李锐海 . Q235钢在广东省输电杆塔现场的大气腐蚀行为[J]. 华南理工大学学报(自然科学版), 2018 , 46(7) : 39 -46 . DOI: 10.3969/j.issn.1000-565X.2018.07.006

Abstract

: The atmospheric corrosion behavior of Q235 steel used as the transmission tower material was investigated systematically in the 10 representative transmission lines of four typical atmospheric environments ( urban,industrial,marine and rural) by field exposure in Guangdong Province for one year. The period for recapturing samples from the field station lasted 6 and 12 months respectively. Their corrosion weight losses in unit area were measured to investigate the corrosion rule of Q235 steel. X-ray diffraction ( XRD) and scanning electron microscopy ( SEM) were applied to analyze the microstructure and morphology of the corrosion products respectively. Results suggested that the atmospheric corrosion grade of a large part of Guangdong Province belongs to C3 and other parts belong to C2,a moderate rank as a whole. The influence of different environments on the atmospheric corrosion is different as follows: the heavy industrial environment,the compound one of marine and light industry,the marine and urban one,the little city and rural one. The corrosion rate of Q235 in the previous 6 months is obviously higher than that in the latter stage from 6 to 12 months in one-year-field exposure. The corrosion products are mainly αFeOOH and γ-FeOOH with net-or needle-like micro morphology,and a small amount of β-FeOOH is observed in the marine environment

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