华南理工大学学报(自然科学版) ›› 2018, Vol. 46 ›› Issue (7): 39-46.doi: 10.3969/j.issn.1000-565X.2018.07.006

• 材料科学与技术 • 上一篇    下一篇

Q235 钢在广东省输电杆塔现场的大气腐蚀行为

高岩1 黄殷辉1 郑志军2 孟晓波3 廖永力3 李锐海3   

  1. 1. 华南理工大学 材料科学与工程学院,广东 广州,510640; 2. 华南理工大学 机械与汽车工程学院,广东 广州,510640; 3. 南方电网科学研究院有限责任公司,广东 广州,510080
  • 收稿日期:2017-09-28 修回日期:2017-10-18 出版日期:2018-07-25 发布日期:2018-06-01
  • 通信作者: 高岩( 1962-) ,女,博士,教授,主要从事大气腐蚀、纳米材料制备与表征等研究 E-mail:meygao@scut.edu.cn
  • 作者简介:高岩( 1962-) ,女,博士,教授,主要从事大气腐蚀、纳米材料制备与表征等研究
  • 基金资助:
    国家自然科学基金资助项目( 51471072)

Atmospheric Corrosion Behavior of Q235 Steel Exposed on Transmission Tower Sites of Guangdong Province

 GAO Yan 1 HUANG Yinhui 1 ZHENG Zhijun2 MENG Xiaobo 3 LIAO Yongli 3 LI Ruihai 3   

  1.  1. School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China; 2. School of Mechanical and Automotive Engineering,South China University of Technology,Guangzhou 510640,Guangdong, China; 3. Electric Power Research Institute,CSG,Guangzhou 510080,Guangdong,China
  • Received:2017-09-28 Revised:2017-10-18 Online:2018-07-25 Published:2018-06-01
  • Contact: 高岩( 1962-) ,女,博士,教授,主要从事大气腐蚀、纳米材料制备与表征等研究 E-mail:meygao@scut.edu.cn
  • About author:高岩( 1962-) ,女,博士,教授,主要从事大气腐蚀、纳米材料制备与表征等研究
  • Supported by:
     Supported by the National Natural Science Foundation of China( 51471072) 

摘要: 基于广东省输电线路分布情况,在城市、工业、海洋和乡村 4 种环境中选取有代 表性的 10 条杆塔线路,通过 1 年的现场暴露实验研究了杆塔用 Q235 钢的大气腐蚀行为, 在 6、12 个月时各取样一次; 利用失重法测量各挂片的单位面积腐蚀失重,研究了不同环 境中的腐蚀失重规律,并采用 X 射线衍射仪( XRD) 和扫描电子显微镜( SEM) 对腐蚀产物 结构和微观形貌进行表征. 结果表明: 广东省大气腐蚀等级主要为 C3,其次为 C2,属于中 度腐蚀; 不同特征的环境对大气腐蚀的影响从重到轻依次为重工业、海洋 + 轻工业复合、 海洋和特大城市、中小型城市及乡村; 在 12 个月的试验周期内,Q235 钢前 6 个月的腐蚀 速率明显高于后 6 个月; 腐蚀产物主要为花瓣网状和细针状结构的 α-FeOOH 和 γFeOOH,在海洋环境中还出现少量 β-FeOOH

关键词: 输电杆塔, Q235 钢, 大气腐蚀行为, 腐蚀失重, 腐蚀等级

Abstract: : The atmospheric corrosion behavior of Q235 steel used as the transmission tower material was investigated systematically in the 10 representative transmission lines of four typical atmospheric environments ( urban,industrial,marine and rural) by field exposure in Guangdong Province for one year. The period for recapturing samples from the field station lasted 6 and 12 months respectively. Their corrosion weight losses in unit area were measured to investigate the corrosion rule of Q235 steel. X-ray diffraction ( XRD) and scanning electron microscopy ( SEM) were applied to analyze the microstructure and morphology of the corrosion products respectively. Results suggested that the atmospheric corrosion grade of a large part of Guangdong Province belongs to C3 and other parts belong to C2,a moderate rank as a whole. The influence of different environments on the atmospheric corrosion is different as follows: the heavy industrial environment,the compound one of marine and light industry,the marine and urban one,the little city and rural one. The corrosion rate of Q235 in the previous 6 months is obviously higher than that in the latter stage from 6 to 12 months in one-year-field exposure. The corrosion products are mainly αFeOOH and γ-FeOOH with net-or needle-like micro morphology,and a small amount of β-FeOOH is observed in the marine environment

Key words: transmission tower, Q235 steel, atmospheric corrosion behavior, corrosion weight loss, corroion grade

中图分类号: