收稿日期: 2013-06-25
修回日期: 2013-08-12
网络出版日期: 2013-11-19
基金资助
国家国际科技合作专项项目(2013DFA41670);广东省科技计划项目(2010A080804020, 2012B010200021)
Effect of Relative Molecular Mass of Amino- Sulfonic Acid- Based Dispersants on Performances of Ceramic Slurry
Received date: 2013-06-25
Revised date: 2013-08-12
Online published: 2013-11-19
Supported by
国家国际科技合作专项项目(2013DFA41670);广东省科技计划项目(2010A080804020, 2012B010200021)
庞煜霞 高菲 邓永红 郭素芳 邱学青 . 相对分子质量对氨基磺酸系陶瓷浆料分散剂性能的影响[J]. 华南理工大学学报(自然科学版), 2013 , 41(12) : 6 -11,23 . DOI: 10.3969/j.issn.1000-565X.2013.12.002
Five fractions of amino- sulfonic acid- based dispersant ASP with different relative molecular mass wereobtained via ultrafiltration,and their influences on the application performances of ceramic slurry were analyzed,with the corresponding mechanism being explored by analyzing the adsorption amount and the Zeta potential of thesefive ASP fractions on black mud particles.The results indicate that (1) the ceramic slurries added ASP fractionswith high relative molecular mass (more than 10000) are of less outflow time,high fluidity,dispersion andlow thixotropy; (2) the adsorption amount of ASP on black mud particles may increase with the relative molecularmass of ASP,thus improving the Zeta potential between black mud particles and enhancing the steric effect,whichmakes ceramic particles disperse better; (3) ASP without ultrafiltration possesses better dispersion property thaneach ultrafiltrated fraction,which means that the ASP fractions with different relative molecular mass work together toendow the ceramic slurry with best performance.This may be related to the improvement of adsorption amount due tothe multi- layer adsorption of ASP fractions with different relative molecular mass on the ceramic particle surface.
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