华南理工大学学报(自然科学版) ›› 2011, Vol. 39 ›› Issue (9): 7-11.doi: 10.3969/j.issn.1000-565X.2011.09.002

• 食品科学与技术 • 上一篇    下一篇

玉米淀粉的热力学性质与消化性

黄强 王婵 罗发兴 扶雄  张斌   

  1. 华南理工大学 轻工与食品学院,广东 广州 510640
  • 收稿日期:2010-11-30 修回日期:2011-03-22 出版日期:2011-09-25 发布日期:2011-08-02
  • 通信作者: 扶雄(1971-),男,博士,教授,主要从事淀粉资源科学与工程研究.E-mail:lfxfu@scut.edu.cn E-mail:fechoh@scut.edu.cn
  • 作者简介:黄强(1976-) ,男,博士,副教授,主要从事淀粉化学理论与技术研究.
  • 基金资助:

    广东省高校优秀青年创新人才培养计划资助项目( x2qsN9100250) ; 广州市科技计划项目( 2010C6-I00031) ;华南理工大学中央高校基本科研业务费专项资金资助项目( 2009ZM0058)

Thermodynamic Property and Digestibility of Corn Starches

Huang Qiang  Wang Chan  Luo Fa-xing  Fu Xiong  Zhang Bin   

  1. School of Light Industry and Food Sciences,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2010-11-30 Revised:2011-03-22 Online:2011-09-25 Published:2011-08-02
  • Contact: 扶雄(1971-),男,博士,教授,主要从事淀粉资源科学与工程研究.E-mail:lfxfu@scut.edu.cn E-mail:fechoh@scut.edu.cn
  • About author:黄强(1976-) ,男,博士,副教授,主要从事淀粉化学理论与技术研究.
  • Supported by:

    广东省高校优秀青年创新人才培养计划资助项目( x2qsN9100250) ; 广州市科技计划项目( 2010C6-I00031) ;华南理工大学中央高校基本科研业务费专项资金资助项目( 2009ZM0058)

摘要: 对4 种不同直链/支链淀粉含量的玉米淀粉( 蜡质玉米淀粉、普通玉米淀粉、Hylon V 和Hylon VII) 的热力学性质及体外消化性进行测定,进一步分析了淀粉热力学性质与消化性的关系.结果表明: 高支( 蜡质和普通) 玉米淀粉与高链玉米淀粉( Hylon V 和Hylon VII) 的热力学性质存在显著差异; 高支玉米淀粉的起糊温度在70℃左右,而高链玉米淀粉( Hylon VII) 在煮沸的情况下也难以糊化; 4 种淀粉的峰值黏度随直链含量升高显著下降; 具有适当直链含量的普通玉米淀粉具有较高的膨胀度,普通玉米淀粉、Hylon V和Hylon VII 在90℃的膨胀度分别为13. 07、5. 63 和4. 54 g /g.差示扫描量热( DSC) 分析结果表明: 蜡质玉米淀粉只有单一的吸热峰,而普通玉米淀粉和高链玉米淀粉还有直链淀粉与脂质复合物吸热峰,但吸热焓值较蜡质玉米淀粉低; 淀粉经蒸煮处理后,糊化温度较低且具有较高膨胀度的普通玉米淀粉的慢消化淀粉含量较高; 而糊化温度较高、膨胀度较低的高链玉米淀粉中的抗性淀粉含量较高.

关键词: 玉米淀粉, 直链淀粉, 热力学性质, 消化性

Abstract:

Four kinds of corn starches with different amylose /amylopectin contents,namely,waxy corn starch,normal corn starch,Hylon Vand Hylon VII,were investigated in the aspects of thermodynamic property and in vitro digestibility,and the relationship between the two properties was further analyzed. It is found that the thermodynamic property difference between the native high-amylopectin ( waxy and normal) corn starches and the high-amylose
( Hylon Vand Hylon VII) ones is great,that the pasting temperatures of the high-amylopectin corn starches are about 70℃,while the high-amylose corn starch ( Hylon VII) is resistant to gelatinization even in the boiling water,that the peak viscosities of four kinds of corn starches varieties significantly decrease with the increase of amylose content,that the normal corn starch with proper amylose content is of high swelling power,and that the swelling powers of normal corn starch,Hylon V and Hylon VII at 90℃ are respectively 13. 07,5. 63 and 4. 54 g /g. DSC analysis reveals that the waxy corn starch is of one single endothermic peak,while both the normal corn starch and the high amylose starch are not only of an additional endothermic peak of amylose-lipid complex but also of a lower total enthalpy change,and that,after the treatment with the boiling water,the normal corn starch with lower pasting temperature and higher swelling power is of higher slowly-digestible starch content,while the high-amylose corn starches with higher pasting temperature and lower swelling power are of higher resistant starch content.

Key words: corn starch, amylose, thermodynamic property, digestibility