华南理工大学学报(自然科学版) ›› 2010, Vol. 38 ›› Issue (4): 18-22,29.doi: 10.3969/j.issn.1000-565X.2010.04.004

• 化学化工 • 上一篇    下一篇

漆酶/介体系统对马尾松TMP打浆性能及纤维形态的影响

彭新文1  李新平2  张素风2  任俊莉1  孙润仓1,3   

  1. 1.华南理工大学 制浆造纸工程国家重点实验室, 广东 广州 510640;2.陕西科技大学 陕西省造纸技术及特种纸品开发重点实验室 ,陕西 西安710021; 3.北京林业大学 生物质化学与技术研究所, 北京 100083
  • 收稿日期:2009-06-24 修回日期:2009-11-17 出版日期:2010-04-25 发布日期:2010-04-25
  • 通信作者: 任俊莉(1978-),女,讲师,主要从事植物资源化学的研究.E-mail:renjunli@scut.edu.cn E-mail:wenwenpeng1229@163.com
  • 作者简介:彭新文(1982-),女,博士生,主要从事植物资源化学的研究.
  • 基金资助:

    国家自然科学基金资助项目(30710103906); 国家“973”计划项目(2010CB732201); 制浆造纸工程国家重点实验室开放基金资助项目(200815); 华南理工大学自然科学青年基金资助项目

Effects of Modification of Laccase/Mediator System on Refining Property and Fiber Morphology of Masson Pine TMP

Peng Xin-wen1  Li Xin-pingZhang Su-feng2  Ren Jun-li1  Sun Run-cang1.3   

  1. 1.State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China;2.Key Laboratory of Paper Technology and Specialty Paper Development of Shaanxi,Shaanxi University of Science & Technology,Xi'an 710021,Shaanxi,China;3.Institute of Biomass Chemistry and Technology,Beijing Forestry University,Beijing 100083,China
  • Received:2009-06-24 Revised:2009-11-17 Online:2010-04-25 Published:2010-04-25
  • Contact: 任俊莉(1978-),女,讲师,主要从事植物资源化学的研究.E-mail:renjunli@scut.edu.cn E-mail:wenwenpeng1229@163.com
  • About author:彭新文(1982-),女,博士生,主要从事植物资源化学的研究.
  • Supported by:

    国家自然科学基金资助项目(30710103906); 国家“973”计划项目(2010CB732201); 制浆造纸工程国家重点实验室开放基金资助项目(200815); 华南理工大学自然科学青年基金资助项目

摘要: 研究了漆酶处理对未漂马尾松热磨机械浆打浆性能及纤维形态的影响,发现:漆酶处理能够使未漂马尾松热磨机械浆(TMP)纤维的胞间层甚至初生壁产生剥蚀,暴露出更多富含碳水化合物的层结构,纤维更容易吸水润涨,纤维结构更加疏松,纤维更加柔软并容易分丝帚化,同时在打浆过程中纤维的切断现象也减少。漆酶处理能较大幅度提高浆料的成纸强度,其裂断长、撕裂指数分别提高37.30%和47.33%,松厚度下降20.33%,并使动态接触角下降。马尾松TMP纤维的漆酶改性是一种有效的改性方式,能够降低打浆能耗,改善打浆效果,提高纸页的结合强度。

关键词: 漆酶改性, 马尾松, 热磨机械浆, 打浆性能, 纤维形态, 纸页性能

Abstract:

This paper deals with the refining property and fiber morphology of thermo-mechanical pulp(TMP) of masson pine modified with laccase/mediator system.The results indicate that,after the modification with laccase/mediator system,the middle lamella and even the primary wall of the fibers corrodes,the content of lignin on the fiber surface decreases,and more layer structure rich in carbohydrates are exposed to water.Thus,the water absorption of the fibers increases,the softness and swelling of the fibers improve,and the refining property improves to some extent.Moreover,it is found that the breaking length and tearing index of the paper sheet formed by the fibers with laccase modification increase by 37.30% and 47.33%,respectively,the bulk decreases by 20.33%,and the contact angle also decreases.It is thus concluded that the laccase modification is effective in improving the refining property of masson pine TMP and the strength of paper sheet.

Key words: laccase modification, masson pine, thermo-chemical pump, refining property, fiber morphology, paper sheet property