华南理工大学学报(自然科学版) ›› 2009, Vol. 37 ›› Issue (12): 32-36.

• 材料科学与技术 • 上一篇    下一篇

含玻璃相固体废物的蒸压反应特性

张志杰1  唐正宇1  柯昌君2   

  1. 1.华南理工大学 材料科学与工程学院, 广东 广州 510640;2.长江大学 城市建设学院, 湖北 荆州 434023
  • 收稿日期:2009-01-04 修回日期:2009-01-18 出版日期:2009-12-25 发布日期:2009-12-25
  • 通信作者: 张志杰(1970-),男,博士,副教授,主要从事生态环境材料的研究. E-mail:imzhang@scut.edu.cn
  • 作者简介:张志杰(1970-),男,博士,副教授,主要从事生态环境材料的研究.
  • 基金资助:

    广东省科技计划项目(2008A030202006);湖北省教育厅自然科学类重点项目(D200712005);佛山市禅城区产学研专项资助项目(200881010)

Autoclaved Performance of Solid Waste Containing Glass Phase

Zhang Zhi-jie Tang Zheng-yu Ke Chang-jun2   

  1. 1 School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China; 2. School of Urban Construction, Yangtze University, Jingzhou 434-023, Hubei, China
  • Received:2009-01-04 Revised:2009-01-18 Online:2009-12-25 Published:2009-12-25
  • Contact: 张志杰(1970-),男,博士,副教授,主要从事生态环境材料的研究. E-mail:imzhang@scut.edu.cn
  • About author:张志杰(1970-),男,博士,副教授,主要从事生态环境材料的研究.
  • Supported by:

    广东省科技计划项目(2008A030202006);湖北省教育厅自然科学类重点项目(D200712005);佛山市禅城区产学研专项资助项目(200881010)

摘要: 通过傅里叶变换红外光谱分析、X射线衍射分析、扫描电镜分析等方法研究了粉煤灰、废玻璃和矿渣等固体废弃物-石灰体系的蒸压反应特性.结果表明:1.2MPa饱和蒸汽压下,固体废弃物的Si-O伸缩振动频率越低,其蒸压样品的结合水量越大,水热反应能力越强;粉煤灰、废玻璃的Si-O伸缩振动频率越低,其蒸压样品的强度越高;矿渣蒸压样品的强度与矿渣的Si-O伸缩振动频率表现出不同于其他两种固体废弃物的规律,这主要是因为矿渣中的活性铝参与了反应,形成大量的水石榴石,导致其蒸压样品的强度下降.

关键词: 固体废物, 蒸压, 红外光谱, X射线衍射, 扫描电子显微镜, 水热反应能力

Abstract:

This paper investigates the autoclaved performance of the systems combining lime and such solid waste as fly ash, waste glass and slag by means of VF-IR, XRD and SEM. The results show that ( 1 ) at a saturated vapor pressure of 1.2 MPa, both the hydrothermal reactivity and the amount of combined water of the autoclaved product have an obvious negative correlation with the Si-O stretching vibration frequency; (2) the compressive strength of the autoclaved product containing fly ash or waste glass also has a negative correlation with the Si-O stretching vibration frequency; and (3) different from the other two products, the autoclaved product containing slag has a positive correlation with the Si-O stretching vibration frequency in terms of compressive strength, because there exists a large amount of hydrogarnet due to the reaction of activated Al in the slag with the lime.

Key words: solid waste, autoclaving, infrared spectrum, X-ray diffraction, scanning electron microscope, hydrothermal reactivity