华南理工大学学报(自然科学版) ›› 2018, Vol. 46 ›› Issue (2): 118-123,139.doi: 10.3969/j.issn.1000-565X.2018.02.017

• 化学化工 • 上一篇    下一篇

污泥与地沟油制混合燃料的燃烧特性

楼波 薛演振    

  1. 华南理工大学 电力学院,广东 广州 510640
  • 收稿日期:2017-08-18 修回日期:2017-09-26 出版日期:2018-02-25 发布日期:2018-01-02
  • 通信作者: 楼波( 1965-) ,男,博士,副教授,主要从事燃烧科学与技术研究. E-mail:loubo@scut.edu.cn
  • 作者简介:楼波( 1965-) ,男,博士,副教授,主要从事燃烧科学与技术研究.
  • 基金资助:
    广东省科技计划项目( 2014A020216005) ;广东省能源清洁利用重点实验室项目( 2013A061401005) 

The Combustion Characteristic and Kinetic of Fuels Constituted with Sludge and Waste Cooking Oil
 

LOU Bo XUE Yanzhen    

  1.  School of Electric Power,South China University of Science and Technology,Guangzhou 510640,Guangdong,China
  • Received:2017-08-18 Revised:2017-09-26 Online:2018-02-25 Published:2018-01-02
  • Contact: 楼波( 1965-) ,男,博士,副教授,主要从事燃烧科学与技术研究. E-mail:loubo@scut.edu.cn
  • About author:楼波( 1965-) ,男,博士,副教授,主要从事燃烧科学与技术研究.
  • Supported by:
    Supported by the Science and Technology Planning Project of Guangdong Province, China( 2014A020216005) 

摘要:  市政污泥和地沟油混合制备新型燃料为废弃物资源化利用提供了新方法. 文中 利用热重-差示扫描量热同步分析仪对不同混合比例( 污泥与地沟油的质量比分别为1∶0.0, 1∶ 0. 1, 1∶ 0. 2, 1∶ 0. 3, 1∶ 0. 4, 0∶ 1. 0) 的燃料燃烧特性进行了研究,结果显示燃烧特性指数 随着地沟油混入比例的增加而增加,而燃尽温度却相反,表明地沟油的混入有利于污泥的 燃烧与燃尽. 通过对10、 20、 30℃ /min 升温速率下 Ozawa-Flynn-wall( OFW) 和 Friedmen 两 种无模型方法反应动力学的分析,并计算平均活化能发现: 混合质量比为 1∶ 0. 3 时,混合 燃料的平均活化能最小,其值分别为 149. 2 kJ/mol( OFW) 和 139. 5 kJ/mol( Friedmen) ,此 时混合燃料还具有较低的燃尽温度( 575. 5℃) . 

关键词: 市政污泥, 地沟油, 混合燃料, 燃烧特性, 活化能 

Abstract:  The new fuels are fabricated by mixing municipal sludge ( MS) with waste cooking oil ( WCO) ,providing a new method for waste resource utilization. The combustion characteristic of fuels with different blending ratios ( the mass ratios between sludge and waste cooking oil are 1∶ 0. 0,1∶ 0. 1,1∶ 0. 2,1∶ 0. 3,1∶ 0. 4,0∶ 1. 0,respectively) are investigated by means of thermogravimetric simultaneous thermal analyzer in the paper,and the result shows that the combustion characteristic indexes increases with the rise of waste cooking oil proportion,while the burnout temperature behaves oppositely,which suggests that the addition of WCO is beneficial for the combustion and burnout of MS. The reaction kinetics is analyzed by Ozawa-Flynn-Wall and Friedmen methods ( two modelfree methods) at the heating rate of 10,20,30℃ /min,finding after calculating the average activation energy that: When the mixing mass ratio is 1∶ 0. 3,the average activation energy of the blended fuel reaches the minimum with the values of 149. 2kJ/mol ( OFW) and 139. 5kJ/mol ( Friedmen) ,respectively,and here the blended fuels at the mass ratio possess a lower burnout temperature ( 575. 5℃) . 

Key words: municipal sludge, waste cooking oil, blended fuel, combustion characteristic, activation energy

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