华南理工大学学报(自然科学版) ›› 2017, Vol. 45 ›› Issue (2): 108-115.doi: 10.3969/j.issn.1000-565X.2017.02.015

• 材料科学与技术 • 上一篇    下一篇

聚酰亚胺纤维纸基复合材料的制备及性能

陈港1 王晨晨1 严致远2 方志强1 朱朋辉1   

  1. 1. 华南理工大学 制浆造纸工程国家重点实验室,广东 广州 510640;2. 中国轻工业武汉设计工程有限责任公司,湖北 武汉 430000
  • 收稿日期:2016-01-04 修回日期:2016-04-26 出版日期:2017-02-25 发布日期:2016-12-31
  • 通信作者: 陈港( 1967-) ,男,教授,博士生导师,主要从事造纸技术与特种纸的研究. E-mail:papercg@scut.edu.cn
  • 作者简介:陈港( 1967-) ,男,教授,博士生导师,主要从事造纸技术与特种纸的研究.
  • 基金资助:

    国家重点基础研究发展计划( 973 计划) 项目( 2010CB732206) ; 广东省教育部产学研专项资金技术前沿项目( 2013B090500071) ; 华南理工大学中央高校基本科研业务费专项资金资助项目( 2015ZM156)

Preparation and Properties of Polyimide Fiber Paper-Based Composite Materials

CHEN Gang1 WANG Chen-chen1 YAN Zhi-yuan2 FANG Zhi-qiang1 ZHU Peng-hui1   

  1. 1.State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China; 2.China Light Industry Wuhan Design &Engineering Co.,Ltd.,Wuhan 430000,Hubei,China
  • Received:2016-01-04 Revised:2016-04-26 Online:2017-02-25 Published:2016-12-31
  • Contact: 陈港( 1967-) ,男,教授,博士生导师,主要从事造纸技术与特种纸的研究. E-mail:papercg@scut.edu.cn
  • About author:陈港( 1967-) ,男,教授,博士生导师,主要从事造纸技术与特种纸的研究.
  • Supported by:
    Supported by the National Program on Key Basic Research Project of China( 973 Program) ( 2010CB732206)

摘要: 以聚酰亚胺短纤和沉析纤维为原料,通过湿法抄造结合热压和树脂浸渍的方法制备聚酰亚胺纤维/环氧树脂纸基复合材料,研究了热压温度、热压压力以及环氧树脂浸渍量对聚酰亚胺纸基复合材料性能的影响. 结果表明,热压处理增加了聚酰亚胺纤维间的接触面积,使聚酰亚胺纤维纸的力学性能和电学性能增强; 采用环氧树脂浸渍处理,可以进一步增加聚酰亚胺纸基复合材料的力学性能( 抗张指数提高了1. 25 倍) 和电学性能( 耐压强度提高了17%) ; 当热压温度为210℃、热压压力为120 N/mm、浸渍量为20%时,所制备的聚酰亚胺纸基复合材料具有较好的力学性能和电学性能,其抗张指数为57. 5 N·m/g,撕裂指数为6. 86mN·m2 /g,耐压强度为12. 3 kV/mm,在航空航天、绝缘阻隔、环境保护等领域具有潜在的应用前景.

关键词: 聚酰亚胺纤维纸, 复合材料, 热压温度, 热压压力, 环氧树脂, 浸渍, 力学性能, 电学性能

Abstract:

Polyimide fiber /epoxy paper-based composite materials were prepared from polyimide chopped fibers and polyimide fibrid fibers by means of wet papermaking combined with hot pressing and resin impregnation,and the effects of hot-pressing temperature,hot-pressing pressure and epoxy resin impregnation increment on the properties of polyimide fiber paper-based composite materials were investigated.The results show that ( 1) after the hot pressing,the contact area of polyimide fibers increases,which results in the improvement of mechanical and electrical properties of the polyimide fiber paper; ( 2) resin impregnation further improves the mechanical and electrical properties of polyimide fiber paper-based composite,concretely,the tensile index increases by 1. 25 fold and the dielectric strength increases by 17%; and ( 3) at a hot-pressing temperature of 210 ℃,a hot-pressing pressure of 120 N/mm and an impregnation increment of 20%,the composite possesses good mechanical and electrical properties,namely a tensile index of 57. 5 N·m/g,a tear index of 6. 86 mN·m2 /g and a dielectric strength of 12. 3 kV/mm,which means that the composite is potentially useful in such fields as aerospace,insulation barrier and environmental protection.

Key words: polyimide fiber paper, composite material, hot-pressing temperature, hot-pressing pressure, epoxy resin, impregnation, mechanical property, electrical property