华南理工大学学报(自然科学版) ›› 2016, Vol. 44 ›› Issue (6): 70-76.doi: 10.3969/j.issn.1000-565X.2016.06.012

• 材料科学与工程 • 上一篇    下一篇

轧制变形对 Al-5Zn-3Mg-1Cu-0.12Zr 合金厚板剥蚀淬火敏感性的影响

李东锋1,2 张新明1,3 尹邦文1,3 刘胜胆1,3 雷越1,3 邓运来1,3   

  1. 1. 中南大学 材料科学与工程学院,湖南 长沙 410083; 2. 湖南工程学院 机械工程学院,湖南 湘潭 411101; 3. 中南大学 教育部有色金属材料科学与工程重点实验室,湖南 长沙 410083
  • 收稿日期:2015-11-27 修回日期:2016-03-02 出版日期:2016-06-25 发布日期:2016-05-03
  • 通信作者: 张新明(1946-),男,博士,教授,主要从事材料科学与工程研究. E-mail:zhangxm_2015@sina.com
  • 作者简介:李东锋(1979-),男,博士生,讲师,主要从事超高强铝合金组织与性能研究. E-mail:hunan_ldf@163. com
  • 基金资助:
    国家重点基础研究发展计划项目(2012CB619500);国际科技合作专项(2013DFG51890)

Effect of Rolling Deformation on Quench Sensitivity to Exfoliation Corrosion of Thick Al-5Zn-3Mg-1Cu-0. 12Zr Alloy Plate

LI Dong-feng1,2 ZHANG Xin-ming1,3 YIN Bang-wen1,3 LIU Sheng-dan1,3 LEI Yue1,3 DENG Yun-lai1,3   

  1. 1.School of Materials Science and Engineering,Central South University,Changsha 410083,Hunan,China; 2.School of Mechanical Engineering,Hunan Institute of Engineering,Xiangtan 411101,Hunan,China; 3.Key Laboratory of Nonferrous Metals Materials of the Ministry of Education,Central South University,Changsha 410083,Hunan,China
  • Received:2015-11-27 Revised:2016-03-02 Online:2016-06-25 Published:2016-05-03
  • Contact: 张新明(1946-),男,博士,教授,主要从事材料科学与工程研究. E-mail:zhangxm_2015@sina.com
  • About author:李东锋(1979-),男,博士生,讲师,主要从事超高强铝合金组织与性能研究. E-mail:hunan_ldf@163. com
  • Supported by:
    Supported by the National Program on Key Basic Research Project of China(2012CB619500)and the Interna-tional S&T Cooperation Program of China(2013DFG51890)

摘要: 采用末端淬火试验、剥落腐蚀浸泡试验、光学显微镜和透射电子显微镜等方法,研究了轧制变形量对 Al-5Zn-3Mg-1Cu-0.12Zr 铝合金厚板剥落腐蚀敏感性的影响. 结果表明:该合金板材的抗剥落腐蚀性能随冷却速率减小而降低,降低程度随热轧变形量的增加而提高,即剥落腐蚀淬火敏感性增加;变形量由56%增加至91%,在冷却速率为2160℃ /min时,剥落腐蚀等级都为 P 级,在冷却速率为 100 ℃ /min 时,剥落腐蚀等级由 EA 级增加至ED 级;变形量分别为 56%、72%、81% 和 91% 时,在冷却速率分别大于 100、159、209 和320℃ /min 的区域,合金剥落腐蚀等级达到或优于 EA 级;在相同轧制变形量下,冷却速率的减小会使合金晶界无沉淀析出带宽化,导致合金抗剥蚀性能变差.

关键词: 铝合金, 轧制变形量, 剥落腐蚀, 淬火敏感性, 晶界析出相

Abstract: This paper deals with the effect of rolling deformation on the quench sensitivity to the exfoliation corro- sion (EXCO) of thick Al-5Zn-3Mg-1Cu-0. 12Zr alloy plates by means of end-quenching testing,corrosion immer- sion testing,optical microscopy and transmission electron microscopy.The results show that (1) the resistance to EXCO of the plate decreases with the decrease in cooling rate,and the decrement of EXCO resistance increases with the increase in hot rolling deformation,which means that there exists an increasing quench sensitivity to EX- CO; (2) when the rolling deformation ranges from 56% to 91%,the exfoliation corrosion levels of all the samples are P at a quench rate of 2160℃ /min,while the level varies from EA to ED at a quench rate of 100℃ /min; (3) when the rolling deformation is 56%,72%,81% and 91%,the exfoliation corrosion level is EA or deeper than EA at the quench rates of more than 100,159,209 and 320 ℃ /min; and (4) under a constant rolling deforma- tion,the precipitate free zone will be widened with the decrease of quench rate,which may result in the degrada- tion of the exfoliation corrosion resistance.

Key words: aluminum alloy, rolling deformation, exfoliation corrosion, quench sensitivity, grain boundary precipitate

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