华南理工大学学报(自然科学版) ›› 2016, Vol. 44 ›› Issue (10): 143-150.doi: 10.3969/j.issn.1000-565X.2016.10.021

• 食品科学与技术 • 上一篇    

凝胶剂对三元油脂凝胶结构及其荷载量的影响

刘国琴 万文博   

  1. 华南理工大学 食品科学与工程学院,广东 广州 510640
  • 收稿日期:2015-09-02 修回日期:2016-05-18 出版日期:2016-10-25 发布日期:2016-09-01
  • 通信作者: 刘国琴(1962-),女,教授,博士生导师,主要从事油脂与植物蛋白研究. E-mail:liuguoqin2009@126.com
  • 作者简介:刘国琴(1962-),女,教授,博士生导师,主要从事油脂与植物蛋白研究.
  • 基金资助:

    国家自然科学基金资助项目(31471677,31271885);国家高技术研究发展计划项目(2013AA102103);公益性行业(农业)科研专项(201303072)

Effects of Structurants on Structure and Loading Capacity of Ternary Organogels

LIU Guo-qin WAN Wen-bo   

  1. School of Food Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2015-09-02 Revised:2016-05-18 Online:2016-10-25 Published:2016-09-01
  • Contact: 刘国琴(1962-),女,教授,博士生导师,主要从事油脂与植物蛋白研究. E-mail:liuguoqin2009@126.com
  • About author:刘国琴(1962-),女,教授,博士生导师,主要从事油脂与植物蛋白研究.
  • Supported by:
    Supported by the National Natural Science Foundation of China(31471677,31271885),the National High-tech Research and Development Project(2013AA102103) and the Public Welfare Industry(Agriculture) Research Project(201303072)

摘要: 以玉米油为基料油,通过添加 3 种不同的凝胶剂(谷甾醇 + 卵磷脂,神经酰胺和乙基纤维素),制备了荷载姜黄素的三元油脂凝胶体系,并探讨了不同凝胶剂对三元油脂凝胶的流变行为、固体脂肪含量等宏观性质及其微观形貌、晶型结构等微观性质以及荷载量的影响. 实验结果表明,谷甾醇 + 卵磷脂与神经酰胺形成的三元凝胶结构相似,都形成纤维状的结晶结构;前者的结构更为紧密,荷载量[(3. 14 ± 0. 10)mg/g]和包埋率[(62. 78 ±2. 01)%]较高;乙基纤维素形成的凝胶结构与前两种有很大不同,其结晶结构为颗粒状,晶体较小,结构较为松散,但是由于其较高的制备温度,它的荷载水平最佳,荷载量和包埋率分别为(4. 810 ±0. 174)mg/g 和(96. 19 ±3. 48)%. 这说明油脂凝胶剂的种类对三元油脂凝胶的性能、微观结构和荷载量都有显著影响.

关键词: 油脂凝胶, 三元体系, 姜黄素, 凝胶剂, 微观结构

Abstract:

Ternary curcumin-organogels were prepared based on corn oil and by using sitosterol + letithin,cera- mide,ethyecellulose as thestructurants.Then,the effects of the structurants on the macroscopic properties (the rheological behaviors,the solid fat content,etc) and the microscopic properties (the microstructures,the crys- talline structure,etc) of ternary organogels were discussed,and the corresponding loading capacities were also evaluated.Experimental results show that (1) the structures of sitosterol + letithin-organogels and ceramide- organogels are similar and are both fibrous crystal structure,and the former exhibits a tighter network with higher encapsulation efficiency (EE) and loading capacity (LC),which are respectively (3. 14 ± 0. 10) mg/g and (62. 78 ±2. 01)%; (2) however,the structure of ethyecellulose-organogelsis totally different from the above two structures,and it is granular with a smaller crystal and relatively loose network; and (3) because of higher prepa- ration temperature.ethyecellulose-organogels show the highest load level,specifically,LC and EE are respectively (4. 810 ±0. 174)mg/g and (96. 19 ±3. 48)%. The above results indicate that the structurants significantly affect the properties,microstructures and loading capacity of organogels.

Key words: organogel, ternary systems, curcumin, structurants, microstructure