华南理工大学学报(自然科学版) ›› 2015, Vol. 43 ›› Issue (7): 1-7.doi: 10.3969/j.issn.1000-565X.2015.07.001

• 材料科学与技术 •    下一篇

不同硅含量铝合金的微弧氧化及膜层特性研究

李康 李文芳 张果戈 段奇   

  1. 华南理工大学 材料科学与工程学院,广东 广州 510640
  • 收稿日期:2015-02-28 修回日期:2015-04-07 出版日期:2015-07-25 发布日期:2015-06-03
  • 通信作者: 李文芳(1964-),男,教授,博士生导师,主要从事金属材料表面工程及复合材料的研究. E-mail:mewfli@scut.edu.cn
  • 作者简介:李康(1987-),男,博士生,主要从事铝合金表面微弧氧化的研究. E-mail: shdlikang@163. com
  • 基金资助:
    广东省自然科学基金资助项目(S2013010015211);华南理工大学中央高校基本科研业务费专项资金资助项目 (2012ZZ0011)

Micro Arc Oxidation and Layer Characteristics of Binary Al-Si Alloys of Different Si Content

Li Kang Li Wen-fang Zhang Guo-ge Duan Qi   

  1. School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2015-02-28 Revised:2015-04-07 Online:2015-07-25 Published:2015-06-03
  • Contact: 李文芳(1964-),男,教授,博士生导师,主要从事金属材料表面工程及复合材料的研究. E-mail:mewfli@scut.edu.cn
  • About author:李康(1987-),男,博士生,主要从事铝合金表面微弧氧化的研究. E-mail: shdlikang@163. com
  • Supported by:
     Supported by the Natural Science Foundation of Guangdong Province(S2013010015211)

摘要: 分别对含硅量为 0.5%、5.0%、9.0% 和 120% 的 4 种铝合金在不同微弧氧化 (MAO)模式下处理 15 min 的成膜过程、膜层特征及能耗等进行了研究,通过 SEM、EDS、 XRD 等对膜层进行了表征. 结果表明:恒流条件下,随基体中硅含量的增加,合金的正向 电压上升速率逐渐减缓,起弧前的等待时间显著延长,起弧电压和放电反应阶段的电压值 也逐渐减小,膜层的平均生长速率明显下降,膜层表面的放电通道孔数目逐渐增多;恒压 条件下,基体中硅含量对铝合金 MAO 的影响相对较弱,当硅元素增加时,合金的正、负向 电流密度均逐渐增大,膜层的生长速率渐渐减小,但它们的表面形貌相差较小;各 Al-Si 合金在恒流和恒压两种 MAO 模式下生成的膜层均主要由 γ-Al2O3 、α-Al2O3 及莫来石组 成,且随基体中硅的增加,Al2O的含量逐渐下降;相同 MAO 模式下,各合金生成的膜层的 单位体积能耗值随其 Si 含量的增加而逐渐增大;此外,同种 Al-Si 合金在不同氧化模式下 制得的 MAO 膜层的特征及能耗差异较大.

关键词: 微弧氧化, Al-Si 合金, 恒流, 恒压, 能耗

Abstract: Four kinds of Al-Si alloys containing 0.5%,5.0%,9.0% and 12.0% Si respectively,were treated by means of the micro arc oxidation (MAO) for 15 min.Then,the MAO layers were investigated in terms of formation process,characteristics and energy consumption,and were characterized by means of SEM,EDS and XRD.The results show that (1) under the MAO treatment at constant current,as the Si content increases,the ascent rate of positive voltage,the striking voltage and the positive voltage during discharge stage,the average growth rate of the layer decease while the pores of discharge channels and the waiting time before spark discharges increase; (2) however,under the MAO treatment at constant voltage,the Si content has a weaker effect on the MAO of Al-Si al- loys,and as the Si content increases,the positive and negative current densities of the alloys both increase and the layers have a gradually-decreasing growth rate but with a similar surface morphology; (3) the layers on Al-Si alloys obtained through the two MAO modes at constant current and constant voltage are both composed of γ-Al2O3,α-Al2O3 and mullite,and the Al2O3 content in the alloys decreases with the increase of the Si content; and (4) the spe- cific energy consumption of the layers obtained through the same MAO mode increases with the Si content.Besides,both the characteristics and energy consumption of the layers on the same alloys through different MAO modes are quite different.

Key words: micro arc oxidation, Al-Si alloys, constant current, constant voltage, energy consumption

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